Highly selective C2H2 and CO2 capture and magnetic properties of a robust Co-chain based metal-organic framework

Ding Tao; Zhang Sheng; Zhang Weiqiang; Zhang Guofang; Gao Zi-Wei

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Highly selective C2H2 and CO2 capture and magnetic properties of a robust Co-chain based metal-organic framework

【24h】

Highly selective C2H2 and CO2 capture and magnetic properties of a robust Co-chain based metal-organic framework

机译：高选择性C2H2和CO2基于稳健的基于连锁金属有机框架的捕获和磁性

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

A robust Co-based metal-organic framework, [Co-3(L)(OH)(2)(H2O)(4)]center dot 2DMF center dot 2H(2)O (1), was synthesized under solvothermal conditions using pyridyl-decorated tetracarboxylic acid, 2,6-di(2', 5'-dicarboxylphenyl) pyridine (H4L). Structural analysis demonstrates that 1 is a 3D framework based on 1D alternate Co-4 chain units. The desolvated structure of 1a contains 1D open channels with a highly polar pore surface decorated with open metal sites, mu(3)-OH group and pyridyl group sites, exhibiting multipoint interactions between C2H2 and CO2 molecules. The framework efficiently takes up C2H2 and CO2 with significant selectivity for C2H2 and CO2 over CH4. In addition, the magnetic properties of 1 were investigated and it showed a slow freezing process.

机译：稳健的Co-3（OH）（2）（2）（2）（2）（2）（4））中心点2DMF中心点2H（2）O（1），在溶剂热条件下合成吡啶基装饰四羧酸，2,6-二（2'，5'-二羧基）吡啶（H4L）。结构分析表明，1是基于1D替代CO-4链单元的3D框架。 1A的脱溶的结构含有1D开放通道，其具有高极性孔表面，具有开放金属位点，MU（3）-OH基团和吡啶基位点，在C 2 H 2和CO 2之间具有多点相互作用。该框架有效地占用C2H2和CO 2，具有显着的C2H2和CO 2上的选择性CH4。另外，研究了1的磁性，并显示出缓慢冷冻过程。

著录项

来源
《Dalton transactions: An international journal of inorganic chemistry》 |2019年第22期|共8页
作者
Ding Tao; Zhang Sheng; Zhang Weiqiang; Zhang Guofang; Gao Zi-Wei;
展开▼
作者单位

Shaanxi Normal Univ Sch Chem &

Chem Engn Minist Educ Key Lab Appl Surface &

Colloid Chem Xian 710062 Shaanxi Peoples R China;

Baoji Univ Arts &

Sci Coll Chem &

Chem Engn Baoji 721013 Peoples R China;

Shaanxi Normal Univ Sch Chem &

Chem Engn Minist Educ Key Lab Appl Surface &

Colloid Chem Xian 710062 Shaanxi Peoples R China;

Shaanxi Normal Univ Sch Chem &

Chem Engn Minist Educ Key Lab Appl Surface &

Colloid Chem Xian 710062 Shaanxi Peoples R China;

Shaanxi Normal Univ Sch Chem &

Chem Engn Minist Educ Key Lab Appl Surface &

Colloid Chem Xian 710062 Shaanxi Peoples R China;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;无机化学;
关键词

相似文献

外文文献
中文文献
专利

1. Highly selective C2H2 and CO2 capture and magnetic properties of a robust Co-chain based metal-organic framework [J] . Ding Tao, Zhang Sheng, Zhang Weiqiang, Dalton transactions: An international journal of inorganic chemistry . 2019,第22期

机译：高选择性C2H2和CO2基于稳健的基于连锁金属有机框架的捕获和磁性
2. Doubly Interpenetrated Metal-Organic Framework for Highly Selective C2H2/CH4 and C2H2/CO2 Separation at Room Temperature [J] . Zhang Ling, Zou Chao, Zhao Min, Crystal growth & design . 2016,第12期

机译：室温下高选择性C2H2 / CH4和C2H2 / CO2分离的双渗透金属有机骨架
3. A microporous metal-organic framework with both open metal and Lewis basic pyridyl sites for highly selective C2H2/CH4 and C2H2/CO2 gas separation at room temperature [J] . Hui Xu, Yabing He, Zhangjing Zhang Journal of Materials Chemistry, A. Materials for energy and sustainability . 2013,第1期

机译：具有开放金属和Lewis碱性吡啶基位点的微孔金属-有机骨架，可在室温下高度选择性地分离C2H2 / CH4和C2H2 / CO2气体
4. Effects of metal-organic framework properties on CO2/H2 separation performance for pre-combustion CO2 capture via pressure swing adsorption [C] . Zoey R. Herm, Joseph A. Swisher, Berend Smit American Chemical Society National Meeting Exposition . 2011

机译：金属有机骨架性能对通过压力波动吸附捕获CO2 / H2分离性能的影响
5. Design and Characterization of Functional Metal-Organic Frameworks for CO2/CH4 and C2H2/CH4 Separation [D] . Alduhaish, Osamah M. 2017

机译：用于CO2 / CH4和C2H2 / CH4分离的功能性金属有机骨架的设计和表征
6. Polyethyleneimine Incorporated Metal-Organic Frameworks Adsorbent for Highly Selective CO2 Capture [O] . Yichao Lin, Qiuju Yan, Chunlong Kong, -1

机译：聚乙烯亚胺并入的金属有机骨架吸附剂用于高度选择性的二氧化碳捕集
7. Multi-Metals CaMgAl Metal-Organic Framework as CaO-based Sorbent to Achieve Highly CO2 Capture Capacity and Cyclic Performance [O] . Szu-Chen Wu, Po-Hsueh Chang, Chieh-Yen Lin, 2020

机译：多金属CAMGAL金属有机框架作为CAO的吸附剂，实现高度二氧化碳捕获容量和循环性能

Highly selective C2H2 and CO2 capture and magnetic properties of a robust Co-chain based metal-organic framework

摘要

著录项

相似文献

相关主题

期刊订阅