Simultaneous expansion of 9,10 boron-doped anthracene in longitudinal and lateral directions

John Alexandra; Kirschner Sven; Fengel Melina K.; Bolte Michael; Lerner Hans-Wolfram; Wagner Matthias

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Simultaneous expansion of 9,10 boron-doped anthracene in longitudinal and lateral directions

机译：在纵向和横向方向上同时扩展9,10硼掺杂的蒽

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Doubly boron-doped anthracenes and pentacenes have been longitudinally and laterally expanded through annulation of thiophene or benzene rings. The obtained series of closely related compounds allowed an assessment of key structure-property relationships with a focus on optoelectronic characteristics. Most of the products are benchtop-stable blue emitters and capable of accepting two electrons in a reversible manner. The syntheses involved late-stage modifications through photocyclization or stepwise oxidative C-C coupling (DDQ/BF3 center dot Et2O) as well as cyclocondensation of ortho-disilylated or -diborylated aryl building blocks.

机译：通过噻吩或苯环的环节纵向和偏向掺杂硼掺杂的蒽酮和五苯磺酸。所获得的一系列密切相关的化合物允许评估关键结构性质关系，重点是光电特征。大多数产品是台式稳定的蓝色发射器，能够以可逆的方式接受两个电子。合成涉及通过光阳离子或逐步氧化C-C偶联（DDQ / BF3中心DOT ET 2 O）以及邻甲硅烷烷基化或替代的芳基构建块的环常见致级修饰。

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《Dalton transactions: An international journal of inorganic chemistry》 |2019年第5期|共7页
作者
John Alexandra; Kirschner Sven; Fengel Melina K.; Bolte Michael; Lerner Hans-Wolfram; Wagner Matthias;
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Goethe Univ Frankfurt Inst Anorgan Chem Max von Laue Str 7 D-60438 Frankfurt Germany;

Goethe Univ Frankfurt Inst Anorgan Chem Max von Laue Str 7 D-60438 Frankfurt Germany;

Goethe Univ Frankfurt Inst Anorgan Chem Max von Laue Str 7 D-60438 Frankfurt Germany;

Goethe Univ Frankfurt Inst Anorgan Chem Max von Laue Str 7 D-60438 Frankfurt Germany;

Goethe Univ Frankfurt Inst Anorgan Chem Max von Laue Str 7 D-60438 Frankfurt Germany;

Goethe Univ Frankfurt Inst Anorgan Chem Max von Laue Str 7 D-60438 Frankfurt Germany;

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正文语种 eng
中图分类化学;无机化学;
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1. Simultaneous expansion of 9,10 boron-doped anthracene in longitudinal and lateral directions [J] . John Alexandra, Kirschner Sven, Fengel Melina K., Dalton transactions: An international journal of inorganic chemistry . 2019,第5期

机译：在纵向和横向方向上同时扩展9,10硼掺杂的蒽
2. 9,10-Dimethyl-9,10-peroxy-9,10-dihydroanthracene [J] . Wang Y.-W. Acta Crystallographica Section E: Crystallographic Communications . 2008,第4期

机译：9,10-二甲基-9,10-过氧-9,10-二氢蒽
3. 9,10-Dimethyl-9,10-peroxy-9,10-dihydroanthracene [J] . Wang Y.-W. Acta Crystallographica Section E: Crystallographic Communications . 2008,第4期

机译：9,10-二甲基-9,10-过氧-9,10-二氢蒽
4. FENTON OXIDATION WITH ETHANOL TO DEGRADE ANTHRACENE INTO BIODEGRADABLE 9,10- ANTHRAQUINON: A PRETREATMENT METHOD FOR ANTHRACENE-CONTAMINATED SOIL [C] . Byung-Dae Lee, Masaaki Hosomi, Akihiko Murakami Biennial conference of the International Association on Water Quality . 1998

机译：Fenton乙醇氧化将蒽降解为可生物降解的9,10-蒽醌：一种被蒽污染的土壤的预处理方法
5. Comparing the Effects of a Hip Strengthening Program and a Lateral Plyometric Program on Lateral Change of Direction Performance [D] . ?Taylor, Jason 2020

机译：比较HIP强化程序的效果和横向锭术计划对方向性能的横向变化
6. Tetramethyl anthracene-2,3,6,7-tetracarboxylate–tetramethyl 9,10-dihydro-9,10-dioxoanthracene-2,3,6,7-tetracarboxylate (1/1) [O] . Brenton L. Drake, J. Larry Morris, Mark L. McLaughlin, 2015

机译：四甲基蒽-2,3,6,7-四羧酸酯-四甲基9,10-二氢-9,10-二氧杂蒽-2,3,6,7-四羧酸酯（1/1）
7. 9,10-Dimethyl-9,10-peroxy-9,10-dihydroanthracene [O] . Wang, Yun-Wu 2008

机译：9,10-二甲基-9,10-过氧9,10-二氢蒽
8. Fluorescence Spectra and Quantum Yields: Quinine, Uranine, 9,10-Diphenylanthracene and 9,10-Bis(Phenylethynyl) Anthracenes. [R] . heller,carl a. henry,ronald a. 1973

机译：光谱和量子产率荧光：奎宁，铀，9,10-二苯基蒽和9,10-双（苯乙炔基）蒽。

Simultaneous expansion of 9,10 boron-doped anthracene in longitudinal and lateral directions

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