Cyanoferrocenes as redox-active metalloligands for coordination-driven self-assembly

Wilkinson Luke A.; Yue Thomas T. C.; Massey Emma; White Andrew J. P.; Long Nicholas J.

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Cyanoferrocenes as redox-active metalloligands for coordination-driven self-assembly

【24h】

Cyanoferrocenes as redox-active metalloligands for coordination-driven self-assembly

机译：Cyanoferrocenes作为氧化还原活性的金属溶胶配体，用于协调驱动的自组装

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Ferrocene-based Lewis bases have found utility as metalloligands in a wide variety of applications. The coordination chemistry of cyanoferrocenes however, is underexplored. Herein, we describe a new synthetic protocol for the generation of cyanoferrocenes. The coordination chemistry of these metalloligands to [Cu(NCMe)(4)][PF6], [(PPh3)(2)Cu(NCMe)(2)][PF6] and [(dppf) Cu(NCMe)(2)][PF6] salts has been explored, providing crystallographic evidence of cluster and polymeric forms of 1,1'- and 1,2-dicyanoferrocene complexes. The stability of the complexes and ligand dissociation were found to be strongly solvent-dependent.

机译：基于Ferrocene的Lewis基地在各种应用中找到了金属溶胶的实用性。然而，氰基苄烯烯的配位化学是望而面的。在此，我们描述了一种用于产生氰基蛋白酶的新的合成方案。这些金属棒配体的配位化学[Cu（NCME）（4）] [PF6]，[（PPH3）（2）Cu（NCME）（2）] [PF6]和[（DPPF）Cu（NCME）（2） [PF6]已经探索了盐，提供了簇的结晶证据和聚合物形式的1,1'-和1,2-二氰芴络合物。发现复合物和配体解离的稳定性是强烈的溶剂依赖性。

著录项

来源
《Dalton transactions: An international journal of inorganic chemistry》 |2019年第1期|共7页
作者
Wilkinson Luke A.; Yue Thomas T. C.; Massey Emma; White Andrew J. P.; Long Nicholas J.;
展开▼
作者单位

Imperial Coll London Mol Sci Res Hub London W12 0BZ England;

Imperial Coll London Mol Sci Res Hub London W12 0BZ England;

Imperial Coll London Mol Sci Res Hub London W12 0BZ England;

Imperial Coll London Mol Sci Res Hub London W12 0BZ England;

Imperial Coll London Mol Sci Res Hub London W12 0BZ England;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;无机化学;
关键词

相似文献

外文文献
中文文献
专利

1. Cyanoferrocenes as redox-active metalloligands for coordination-driven self-assembly [J] . Wilkinson Luke A., Yue Thomas T. C., Massey Emma, Dalton transactions: An international journal of inorganic chemistry . 2019,第1期

机译：Cyanoferrocenes作为氧化还原活性的金属溶胶配体，用于协调驱动的自组装
2. Facile self-assembly of supramolecular hexakisferrocenyl triangles via coordination-driven self-assembly and their electrochemical behavior [J] . Zhao G.-Z., Li Q.-J., Chen L.-J., Organometallics . 2011,第13期

机译：通过配位驱动的自组装的超分子六亚铁二茂铁基三角形的容易的自组装及其电化学行为
3. Titanium thiosalicylate complexes: functional metalloligands for the construction of redox-active heterometallic architectures [J] . Fandos Rosa, Bruna Sonia, Hernandez Carolina, Dalton transactions: An international journal of inorganic chemistry . 2018,第43期

机译：硫化钛酸酯复合物：用于氧化还原活性的杂动机架构的函数金属溶胶配体
4. Coordination-driven self-assembly of multi-chromophoric architectures using photoactive building blocks [C] . Timothy R. Cook, Austin B. Gilbert, Cory E. Hauke, Conference on Organic Photonic Materials and Devices . 2021

机译：使用光活性构建块协调驱动多发色体架构的自组装
5. Synthesis, Characterization, and Electronic Structure of Heteromultimetallic Complexes Incorporating a Redox-Active Metalloligand [D] . Wojnar, Michael Kenneth. 2019

机译：含氧化还原活性金属配体的杂多金属配合物的合成，表征和电子结构
6. Coordination-Driven Self-Assembly of M3L2 Trigonal Cages from Pre-organized Metalloligands Incorporating Octahedral Metal Centers and Fluorescent Detection of Nitroaromatics [O] . Ming Wang, Vaishali Vajpayee, Sankarasekaran Shanmugaraju, -1

机译：来自预组织的金属胶质体的M3L2三角笼的协调自组装含有八面体金属中心和硝基甲甲基荧光学的荧光检测
7. Coordination-Driven Self-Assembly of M3L2 Trigonal Cages from Preorganized Metalloligands Incorporating Octahedral Metal Centers and Fluorescent Detection of Nitroaromatics [O] . Wang, Ming, Vajpayee, Vaishali, Shanmugaraju, Sankarasekaran, 2011

机译：M3L2三角笼的协调驱动自组装，包括三面体金属中心的预组织金属配体和硝基芳烃的荧光检测。

Cyanoferrocenes as redox-active metalloligands for coordination-driven self-assembly

摘要

著录项

相似文献

相关主题

期刊订阅