The experimental determination of Th(iv)/Th(iii) redox potentials in organometallic thorium complexes

Inman Christopher J.; Cloke F. Geoffrey N.

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The experimental determination of Th(iv)/Th(iii) redox potentials in organometallic thorium complexes

机译：有机金属钍复合物中的TH（IV）/ TH（III）氧化还原电位的实验测定

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The first Th-IV/Th-III redox couple values have been determined experimentally using cyclic voltammetry (CV), which has been facilitated by the use of [(Bu4N)-Bu-n][BPh4] as a supporting electrolyte in THF. Th(iv) and Th(iii) metallocene compounds have been studied and their redox couple values are in the range of -2.96 V to -3.32 V vs FeCp2+/0.

机译：首先使用循环伏安法（CV）确定第一Th-IV / TH-III氧化还原耦合值，该循环伏安法（CV）通过使用[（BU4N）-BU-N] [BPH4]作为THF的支撑电解质而促进。已经研究了（IV）和TH（III）茂金属化合物，其氧化还原耦合值在-2.96V至-3.32V VS FECP2 + / 0的范围内。

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《Dalton transactions: An international journal of inorganic chemistry》 |2019年第29期|共3页
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Inman Christopher J.; Cloke F. Geoffrey N.;
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Univ Sussex Sch Life Sci Dept Chem Brighton BN1 9QJ E Sussex England;

Univ Sussex Sch Life Sci Dept Chem Brighton BN1 9QJ E Sussex England;

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正文语种 eng
中图分类化学;无机化学;
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The experimental determination of Th(iv)/Th(iii) redox potentials in organometallic thorium complexes

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