The lanthanide complexes of 2,2'- bipyridyl-6,6'dicarboxylic dimethylanilides: the influence of a secondary coordination sphere on the stability, structure, luminescence and f- element extraction

Borisova Nataliya E.; Sumyanova Tsagana B.; Kharcheva Anastasia V.; Matveev Petr I.; Ivanov Alexey V.; Razumova Elizaveta A.; Patsaeva Svetlana V.

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >The lanthanide complexes of 2,2'- bipyridyl-6,6'dicarboxylic dimethylanilides: the influence of a secondary coordination sphere on the stability, structure, luminescence and f- element extraction

【24h】

The lanthanide complexes of 2,2'- bipyridyl-6,6'dicarboxylic dimethylanilides: the influence of a secondary coordination sphere on the stability, structure, luminescence and f- element extraction

机译：2,2'-双吡啶-6,6'Dicarboxic二甲基硅氧烷的镧系元络合物：二次配位球体对稳定性，结构，发光和F元素提取的影响

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Four of the six possible isomeric 2,2-bipyridyl-6,6-dicarboxylic dimethylanilides were studied from the point of view of the impact of a secondary coordination sphere on the formation of complexes with lanthanides in solution, as well as the crystal structure and photophysical properties of the complexes. All ligands form complexes with a 1:1 metal-to-ligand ratio with an lg(1) in the range of 6.0-8.8, and strong correlations between secondary coordination sphere modulation and stability of the complexes within the lanthanide series. Although substitution at the o-position of the aromatic ring leads to significant elongation of M-O-L bonds in a crystal, this significantly affects the stability of the complexes. The luminescence of the complexes is the most effective for europium complexes. From luminescence measurements of gadolinium complexes, the triplet energy levels of ligands were located as follows: o-methylated ligands show 10% higher levels than other isomers. Also, o-methylation of the phenyl ring increases the lifetime value while m-methylation reduces this value.

机译：六个可能的异构2,2-联吡啶基-6,6-二羧酸dimethylanilides的四个被从考虑到对形成的复合物的与镧系元素溶液的二次配位球的冲击点的研究，以及晶体结构和配合物的光物理特性。所有配体形成具有1络合物：1金属到配体的比率与在6.0-8.8范围内的LG（1），和第二配位球调制和镧系中的配合物的稳定性之间的强相关性。虽然在芳香环，因而在晶体的M-O-L键显著伸长的邻位取代，这显著影响复合物的稳定性。该复合物的发光是最有效的铕络合物等。从钆复合物的发光测量，配体的三重态能量水平位于如下：邻二甲基化的配体显示出更高的10％的水平比其它异构体。另外，苯环的邻 - 甲基化增加了寿命值而M-甲基化降低了此值。

著录项

来源
《Dalton transactions: An international journal of inorganic chemistry》 |2018年第46期|共11页
作者
Borisova Nataliya E.; Sumyanova Tsagana B.; Kharcheva Anastasia V.; Matveev Petr I.; Ivanov Alexey V.; Razumova Elizaveta A.; Patsaeva Svetlana V.;
展开▼
作者单位

Moscow MV Lomonosov State Univ Dept Chem 1-3 Leninskie Gory Moscow 119991 Russia;

Moscow MV Lomonosov State Univ Dept Chem 1-3 Leninskie Gory Moscow 119991 Russia;

Moscow MV Lomonosov State Univ Dept Chem 1-3 Leninskie Gory Moscow 119991 Russia;

Moscow MV Lomonosov State Univ Dept Chem 1-3 Leninskie Gory Moscow 119991 Russia;

Moscow MV Lomonosov State Univ Dept Chem 1-3 Leninskie Gory Moscow 119991 Russia;

Moscow MV Lomonosov State Univ Dept Chem 1-3 Leninskie Gory Moscow 119991 Russia;

Lomonosov Moscow State Univ Fac Phys 1-2 Leninskie Gory Moscow 119991 Russia;

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类化学;无机化学;
关键词

相似文献

外文文献
中文文献

1. The lanthanide complexes of 2,2'- bipyridyl-6,6'dicarboxylic dimethylanilides: the influence of a secondary coordination sphere on the stability, structure, luminescence and f- element extraction [J] . Borisova Nataliya E., Sumyanova Tsagana B., Kharcheva Anastasia V., Dalton transactions: An international journal of inorganic chemistry . 2018,第46期

机译：2,2'-双吡啶-6,6'Dicarboxic二甲基硅氧烷的镧系元络合物：二次配位球体对稳定性，结构，发光和F元素提取的影响
2. Lanthanide coordination polymer constructed from 2,2 '-bipyridyl-4,4 '-dicarboxylic acid: Structure, catalysis and fluorescence [J] . Wang Shengyan, Xu Jianing, Zheng Jifu, Inorganica Chimica Acta . 2015,第Null期

机译：由2,2'-联吡啶-4,4'-二羧酸构造的镧系配位聚合物：结构，催化和荧光
3. Syntheses, structures, luminescence, and magnetic properties of one-dimensional lanthanide coordination polymers with a rigid 2,2'-Bipyridine-3,3',6,6'-tetracarboxylic acid ligand [J] . Ji B., Deng D., He X., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2012,第4期

机译：具有刚性2,2'-联吡啶-3,3'，6,6'-四羧酸配体的一维镧系配位聚合物的合成，结构，发光和磁性
4. The influence of water and temperature on complexes of lanthanides with 6,6′-Bis(diphenylphosphinoyl)-2,2′-bipyridyl [C] . Ts. Sumyanova, D. Kharitonov, A. Kharcheva, International Conference on Pulsed Lasers and Laser Applications . 2019

机译：水和温度对6,6'-双（二苯基膦酰基）-2,2'-双吡啶基镧系元素复合物的影响
5. Effect of Heterocyclic Ring on LnIII Coordination Luminescence and Extraction of Diamides of 22′-Bipyridyl-66′-Dicarboxylic Acid [O] . Nataliya E. Borisova, Alexey V. Ivanov, Anastasia V. Kharcheva, 2020

机译：杂环对22-联吡啶-66-二羧酸二酰胺的LnIII配位发光和萃取的影响
6. Several Factors Influencing the Stability of Extracted Species in Synergistic Extraction of Lanthanide(III) with Pivaloyltrifluoroacetone and 2,2'-Bipyridyl [O] . Tadahisa SAITO, Kazuaki SATO, Mitsunobu MIRATSU, 2010

机译：利用戊丙酮氟丙酮和2,2'-双吡啶协同提取中提取物种中提取物种稳定性的几个因素

The lanthanide complexes of 2,2'- bipyridyl-6,6'dicarboxylic dimethylanilides: the influence of a secondary coordination sphere on the stability, structure, luminescence and f- element extraction

摘要

著录项

相似文献

相关主题

期刊订阅