Solvent effects on the crystal structure of silver pentacyanocyclopentadienide: supramolecular isomerism and solvent coordination

Nimax P. R.; Reimann D.; Suenkel K.

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Solvent effects on the crystal structure of silver pentacyanocyclopentadienide: supramolecular isomerism and solvent coordination

机译：溶剂效应银五氰基氰基碳十二iNINE的晶体结构：超分子异构性和溶剂配位

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Several coordination polymers of silver(i)-pentacyanocyclopentadienide (PCC) were studied by X-ray diffraction to examine the effects of different solvents on supramolecular isomerism of the PCC-ligand. While alcohols yield supramolecular isomers of [Ag(PCC)] without coordination of solvent molecules, less polar solvents show coordinate binding. The influence of solvent polarity can be observed by a gradual change in the lattice structure featuring distinct motifs.

机译：通过X射线衍射研究了若干银（I） - 戊酰基环戊酰胺（PCC）的配位聚合物，以检测不同溶剂对PCC配体的超分子异构性的影响。虽然醇产生[Ag（PCC）]的超分子异构体，但无需协调溶剂分子，极性溶剂显示坐标结合。可以通过晶格结构的逐渐变化观察溶剂极性的影响，其特征在于具有不同的基序。

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《Dalton transactions: An international journal of inorganic chemistry》 |2018年第25期|共7页
作者
Nimax P. R.; Reimann D.; Suenkel K.;
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Ludwig Maximilians Univ Munchen Dept Chem Butenandtstr 5-13 D-81377 Munich Germany;

Ludwig Maximilians Univ Munchen Dept Chem Butenandtstr 5-13 D-81377 Munich Germany;

Ludwig Maximilians Univ Munchen Dept Chem Butenandtstr 5-13 D-81377 Munich Germany;

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正文语种 eng
中图分类化学;无机化学;
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1. Solvent effects on the crystal structure of silver pentacyanocyclopentadienide: supramolecular isomerism and solvent coordination [J] . Nimax P. R., Reimann D., Suenkel K. Dalton transactions: An international journal of inorganic chemistry . 2018,第25期

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Solvent effects on the crystal structure of silver pentacyanocyclopentadienide: supramolecular isomerism and solvent coordination

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