Difuryl(supermesityl)borane: a versatile building block for extended -conjugated materials

Riensch Nicolas A.; Fritze Lars; Schindler Tobias; Kremer Marius; Helten Holger

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Difuryl(supermesityl)borane: a versatile building block for extended -conjugated materials

机译：Difuryl（Supermesityl）硼烷：延伸 - 缀合材料的多功能构件块

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Direct functionalization and Pd-catalyzed cross-coupling of difuryl(supermesityl)borane (1) led to highly emissive organoborane compounds 3 and 4. Photophysical and TD-DFT studies reveal an increase of the HOMO levels with higher hetarene content and stabilization of the HOMO and LUMO levels through B-doping, leading to very robust, air-stable electron-accepting materials.

机译：双核（Supermesityl）硼烷（1）的直接官能化和PD催化的交联偶联LED至高发光的有机硼烷3和4.光物理和TD-DFT研究揭示了具有较高的对arene含量和HOMO的稳定性的HOMO水平的增加和Lumo水平通过B掺杂，导致非常坚固，空气稳定的电子接受材料。

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来源
《Dalton transactions: An international journal of inorganic chemistry》 |2018年第31期|共5页
作者
Riensch Nicolas A.; Fritze Lars; Schindler Tobias; Kremer Marius; Helten Holger;
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Rhein Westfal TH Aachen Inst Inorgan Chem Landoltweg 1 D-52056 Aachen Germany;

Rhein Westfal TH Aachen Inst Inorgan Chem Landoltweg 1 D-52056 Aachen Germany;

Rhein Westfal TH Aachen Inst Inorgan Chem Landoltweg 1 D-52056 Aachen Germany;

Rhein Westfal TH Aachen Inst Inorgan Chem Landoltweg 1 D-52056 Aachen Germany;

Rhein Westfal TH Aachen Inst Inorgan Chem Landoltweg 1 D-52056 Aachen Germany;

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正文语种 eng
中图分类化学;无机化学;
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1. Difuryl(supermesityl)borane: a versatile building block for extended -conjugated materials [J] . Riensch Nicolas A., Fritze Lars, Schindler Tobias, Dalton transactions: An international journal of inorganic chemistry . 2018,第31期

机译：Difuryl（Supermesityl）硼烷：延伸 - 缀合材料的多功能构件块
2. Aldehyde-functionalized dithienylethenes with extended pi-systems as versatile building blocks for NIR photochromic materials [J] . Li Ziyong, Qin Ming, Du Xiaotong, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2019,第42期

机译：具有扩展PI-Systems的醛官能化二苯基氯替代，作为NIR光致变色材料的多功能积木
3. Thieno[3,4-b]pyrazines and its extended analogs: Important buildings blocks for conjugated materials [J] . Rasmussen S.C., Mulholland M.E., Schwiderski R.L., Journal of Heterocyclic Chemistry: The International Journal of Heterocyclic Chemistry . 2012,第3期

机译：噻诺[3,4-b]吡嗪及其扩展类似物：共轭材料的重要组成部分
4. Controlled radical polymerizations as versatile synthetic routes for conjugated rod-coil block copolymers and their use as active polymer semiconducting materials in flexible organic electronic devices and systems [C] . Cyril Brochon, Georges Hadziioannou ACS symposium on controlled/living radical polymerization . 2009

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5. Polyhedral Boranes: A Versatile Building Block for Nanoporous Materials. [D] . Clingerman, Daniel Jon. 2014

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Difuryl(supermesityl)borane: a versatile building block for extended -conjugated materials

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