Silver nanoparticle embedded copper oxide as an efficient core-shell for the catalytic reduction of 4-nitrophenol and antibacterial activity improvement

Bouazizi N.; Vieillard J.; Thebault P.; Desriac F.; Clamens T.; Bargougui R.; Couvrat N.; Thoumire O.; Brun N.; Ladam G.; Morin S.; Mofaddel N.; Lesouhaitier O.; Azzouz A.; Le Derf F.

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Silver nanoparticle embedded copper oxide as an efficient core-shell for the catalytic reduction of 4-nitrophenol and antibacterial activity improvement

机译：银纳米粒子嵌入氧化铜作为一种有效的核心壳，用于催化还原4-硝基苯酚和抗菌活性改善

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A facile and eco-friendly method was developed to prepare a microporous CuO@Ag-0 core-shell with high catalytic and antibacterial activities. Scanning and transmission electron microscopy revealed a preponderance of nearly spherical 50 nm particles with slight structure compaction. Comparison of the hysteresis loops confirmed the structure compaction after AgNP incorporation, and a significant decrease of the specific surface area from 55.31 m(2) g(-1) for CuO to 8.03 m(2) g(-1) for CuO@Ag-0 was noticed. A kinetic study of 4-nitrophenol (4-NP) reduction into 4-aminophenol (4-AP) with sodium borohydride revealed a first order reaction that produces total conversion in less than 18 minutes. CuO@Ag-0 also exhibited appreciable antibacterial activity against Staphylococcus aureus. The antibacterial effects were found to strongly depend on the size, contact surface, morphology and chemical composition of the catalyst particles. The addition of Ag-0-NPs produced more reactive oxygen species in the bacteria medium. These results open promising prospects for its potential applications as a low cost catalyst in wastewater treatment and antibacterial agent in cosmetics.

机译：开发了一种容易和环保的方法，以制备具有高催化和抗菌活性的微孔CuO @ Ag-0核壳。扫描和透射电子显微镜显示出几乎球形50nm粒子的优势，具有轻微的结构压实。滞后环的比较证实了AgNP掺入之后的结构压实，并且对于CuO @ Ag的CuO至8.03m（2）G（-1）的比55.31m（2）g（-1）的比表面积显着降低-0被注意到了。将4-硝基苯酚（4-NP）还原成4-氨基苯酚（4-AP）的动力学研究含硼氢化钠显示出在少于18分钟的总转化物中产生的第一阶反应。 CuO @ Ag-0也表现出对葡萄球菌的可观抗菌活性。发现抗菌作用强烈取决于催化剂颗粒的尺寸，接触表面，形态和化学组成。添加Ag-0-NPS在细菌培养基中产生了更多的反应性氧。这些结果开放了其潜在应用的希望前景，作为废水处理中的低成本催化剂和化妆品中的抗菌剂。

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《Dalton transactions: An international journal of inorganic chemistry》 |2018年第27期|共13页
作者
Bouazizi N.; Vieillard J.; Thebault P.; Desriac F.; Clamens T.; Bargougui R.; Couvrat N.; Thoumire O.; Brun N.; Ladam G.; Morin S.; Mofaddel N.; Lesouhaitier O.; Azzouz A.; Le Derf F.;
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Normandie Univ UNIROUEN INSA Rouen CNRS COBRA UMR 6014 55 Rue St Germain F-27000 Evreux France;

Normandie Univ UNIROUEN INSA Rouen CNRS COBRA UMR 6014 55 Rue St Germain F-27000 Evreux France;

Normandie Univ UNIROUEN CNRS PBS UMR 6270 Batiment Pierre Louis DULONG F-76821 Mont St Aignan France;

IUT Evreux EA 4312 LMSM 55 Rue St Germain F-27000 Evreux France;

IUT Evreux EA 4312 LMSM 55 Rue St Germain F-27000 Evreux France;

Normandie Univ UNIROUEN INSA Rouen CNRS COBRA UMR 6014 55 Rue St Germain F-27000 Evreux France;

Normandie Univ UNIROUEN SMS EA 3233 Rue Tesniere F-76000 Mont St Aignan France;

Normandie Univ UNIROUEN PBS UMR 6270 Ctr Univ CNRS 1 Rue 7eme Chasseur F-27000 Evreux France;

Univ Montpellier Inst Charles Gerhardt Montpellier UMR 5253 CNRS ENSCM F-34095 Montpellier France;

Normandie Univ UNIROUEN PBS UMR 6270 Ctr Univ CNRS 1 Rue 7eme Chasseur F-27000 Evreux France;

Normandie Univ UNIROUEN PBS UMR 6270 Ctr Univ CNRS 1 Rue 7eme Chasseur F-27000 Evreux France;

Normandie Univ UNIROUEN INSA Rouen CNRS COBRA UMR 6014 55 Rue St Germain F-27000 Evreux France;

IUT Evreux EA 4312 LMSM 55 Rue St Germain F-27000 Evreux France;

Univ Quebec Montreal Dept Chem Nanoqam Montreal PQ H3C 3P8 Canada;

Normandie Univ UNIROUEN INSA Rouen CNRS COBRA UMR 6014 55 Rue St Germain F-27000 Evreux France;

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专利

1. Silver nanoparticle embedded copper oxide as an efficient core-shell for the catalytic reduction of 4-nitrophenol and antibacterial activity improvement [J] . Bouazizi N., Vieillard J., Thebault P., Dalton transactions: An international journal of inorganic chemistry . 2018,第27期

机译：银纳米粒子嵌入氧化铜作为一种有效的核心壳，用于催化还原4-硝基苯酚和抗菌活性改善
2. In situ green synthesis of Ag nanoparticles on herbal tea extract (Stachys lavandulifolia)-modified magnetic iron oxide nanoparticles as antibacterial agent and their 4-nitrophenol catalytic reduction activity [J] . Marjan Shahriary, Hojat Veisi, Malak Hekmati, Materials science & engineering . 2018,第SEPa期

机译：以凉茶提取物（Stachys lavandulifolia）-修饰的磁性氧化铁纳米粒子为抗菌剂原位绿色合成Ag纳米粒子及其4-硝基苯酚催化还原活性
3. In situ green synthesis of Ag nanoparticles on herbal tea extract (Stachys lavandulifolia)-modified magnetic iron oxide nanoparticles as antibacterial agent and their 4-nitrophenol catalytic reduction activity [J] . Shahriary Marjan, Veisi Hojat, Hekmati Malak, Materials science & engineering, C. Materials for Biogical applications . 2018,第期

机译：原位绿色合成中药茶提取物（Stachys Lavandulifolia）制型磁性氧化铁纳米粒子作为抗菌剂及其4-硝基酚催化还原活性的Ag纳米粒子
4. Synthesis of nature polymer supported Au, Ag and Au-Ag nanoparticles in aqueous medium and catalytic activity towards 4-nitrophenol reduction [C] . Chou Chih Wei, Hsieh Hui-Hsuan Proceedings of the 2011 6th IEEE International Conference on Nano/Micro Engineered and Molecular Systems . 2011

机译：水性介质中天然聚合物负载的Au，Ag和Au-Ag纳米粒子的合成及其对4-硝基苯酚还原的催化活性
5. Activity and stability of silver-alumina catalysts for the selective catalytic reduction of nitric oxides with methane. [D] . She, Xiaoyan. 2006

机译：银-氧化铝催化剂对甲烷选择性催化还原一氧化氮的活性和稳定性。
6. Silver-Nanoparticles Embedded Pyridine-Cholesterol Xerogels as Highly Efficient Catalysts for 4-nitrophenol Reduction [O] . Ganesh Shimoga, Eun-Jae Shin, Sang-Youn Kim 2020

机译：银-纳米颗粒嵌入的吡啶-胆固醇干凝胶是4-硝基苯酚还原的高效催化剂
7. Green syntheses of silver nanoparticle decorated reduced graphene oxide using l-methionine as a reducing and stabilizing agent for enhanced catalytic hydrogenation of 4-nitrophenol and antibacterial activity [O] . Neway Belachew, Desta Shumuye Meshesha, Keloth Basavaiah 2019

机译：银纳米粒子的绿色合成用L-甲硫氨酸装饰了石墨烯氧化物作为还原和稳定剂，用于增强4-硝基苯酚和抗菌活性的催化氢化剂

Silver nanoparticle embedded copper oxide as an efficient core-shell for the catalytic reduction of 4-nitrophenol and antibacterial activity improvement

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