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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Enhanced acetone sensing performance of Au nanoparticle modified porous tube-like ZnO derived from rod-like ZIF-L
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Enhanced acetone sensing performance of Au nanoparticle modified porous tube-like ZnO derived from rod-like ZIF-L

机译:增强丙酮的丙酮感测性能的Au纳米粒子改性多孔管状ZnO衍生自棒状ZIF-L的ZnO

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摘要

Metal oxide semiconductors with a porous hollow structure have received great attention in many fields. In this work, a facile preparation method of porous tube-like ZnO (PT-ZnO) was developed by annealing rod-like ZIF-L at high temperature, and the formation mechanism of the tube-like structure was discussed in detail. The corresponding gas sensing performances were determined adopting acetone as the target gas. Gas-sensing test results show that PT-ZnO has better acetone sensing performance than that of porous plate-like ZnO (PP-ZnO) derived from leaf-like ZIF-L, resulting from the unique tube-like structure and larger amount of adsorbed oxygen. It is found that the introduction of Au nanoparticles greatly improves the acetone sensing performance, which can be attributed to the activation of acetone by Au and the increased amount of adsorbed oxygen. Au/PT-ZnO has the largest amount of adsorbed oxygen which even becomes the dominant oxygen species on the surface of PT-ZnO, resulting in the best acetone-sensing performance.
机译:具有多孔空心结构的金属氧化物半导体在许多领域中受到了极大的关注。在这项工作中,通过在高温下通过退火棒状ZIF-L开发了多孔管状ZnO(Pt-ZnO)的容易制备方法,详细讨论了管状结构的形成机理。确定相应的气体感测性能,其采用丙酮作为靶气体。气体传感测试结果表明,Pt-ZnO具有比叶状ZIF-L衍生的多孔板ZnO(PP-ZnO)的丙酮感测性能更好,由独特的管状结构和较大量的吸附产生氧。结果发现,Au纳米粒子的引入大大提高了丙酮的感测性能,这可以归因于Au和增加的吸附氧量的丙酮。 Au / Pt-ZnO具有最多的吸附氧,甚至成为Pt-ZnO表面上的主要氧物质,导致最佳的丙酮感测性能。

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    Beijing Univ Civil Engn &

    Architecture Belling Key Lab Funct Mat Bldg Struct &

    Environm Beijing 100044 Peoples R China;

    Beijing Univ Civil Engn &

    Architecture Belling Key Lab Funct Mat Bldg Struct &

    Environm Beijing 100044 Peoples R China;

    Beijing Univ Civil Engn &

    Architecture Belling Key Lab Funct Mat Bldg Struct &

    Environm Beijing 100044 Peoples R China;

    Beijing Univ Chem Technol State Key Lab Chem Resource Beijing 100029 Peoples R China;

    Beijing Univ Civil Engn &

    Architecture Belling Key Lab Funct Mat Bldg Struct &

    Environm Beijing 100044 Peoples R China;

    Beijing Univ Civil Engn &

    Architecture Belling Key Lab Funct Mat Bldg Struct &

    Environm Beijing 100044 Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;无机化学;
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