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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Selective aerobic oxidation of halides and amines with an inorganic-ligand supported zinc catalyst
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Selective aerobic oxidation of halides and amines with an inorganic-ligand supported zinc catalyst

机译:选择性有氧氧化卤化物和胺,含有无机 - 配体的锌催化剂

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摘要

A practical, efficient and environmentally benign catalytic protocol for the oxidative cross-coupling reaction of halides with amines, oxidative self-coupling of amines and oxidation of halides was developed with inorganic-ligand supported ZnPOM (NH4)(4)[ZnMo6O18(OH)(6)] using molecular oxygen. This method mainly utilizes an inorganic polymolybdate ligand to support the Zn2+ ion, avoiding the use of complicated organic ligands.
机译:具有胺的卤化物氧化交联反应的实用,高效且环境良性的催化方案,氧化胺和卤化物氧化的氧化自耦合用无机 - 配体支持的ZnPom(NH4)(4)(4)[ZnMO6O18(OH) (6)]使用分子氧。 该方法主要利用无机聚钼酸甲酸盐配体来支撑Zn2 +离子,避免使用复杂的有机配体。

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    Shanghai Inst Technol Sch Chem &

    Environm Engn Shanghai 201418 Peoples R China;

    Shanghai Inst Technol Sch Chem &

    Environm Engn Shanghai 201418 Peoples R China;

    Shanghai Inst Technol Sch Chem &

    Environm Engn Shanghai 201418 Peoples R China;

    Shanghai Inst Technol Sch Chem &

    Environm Engn Shanghai 201418 Peoples R China;

    Shanghai Univ Tradit Chinese Med Longhua Hosp 725 South Wanping Rd Shanghai 200032 Peoples R China;

    Tsinghua Univ Dept Chem Minist Educ Key Lab Organ Optoelect &

    Mol Engn Beijing 100084 Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;无机化学;
  • 关键词

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