...
首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >The role of coordinated solvent on Co(II) ions in tuning the single molecule magnet properties in a {(Co2Dy2III)-Dy-II} system
【24h】

The role of coordinated solvent on Co(II) ions in tuning the single molecule magnet properties in a {(Co2Dy2III)-Dy-II} system

机译:协调溶剂对CO(II)离子在{(CO2DY2IIII)-II-II}系统中的单分子磁体特性调节CO(II)离子的作用

获取原文
获取原文并翻译 | 示例
           

摘要

Three defect-dicubane coordination clusters related to our previously reported butterfly compound, [Co2Dy2(L)(4)(NO3)(2)(THF)(2)]center dot 4THF (1) and formulated as [Co2Dy2(L)(4)(NO3)(2)(MeOH)(2)]center dot 2CH(2)Cl(2) (2), [Co2Dy2(L) (4)(NO3) (2)(DMF)(2)]center dot 2C(2)H(6)CO (3) and [Zn2Dy2(L)(4)(NO3)(2)(MeOH)(2)]center dot 2CH(2)Cl(2) (4) were synthesised and characterised. All show typical SMM behaviour which is steered through the nature of the solvent molecule coordinated to the central 3d ions. The (Zn2Dy2III)-Dy-II, (4) provides experimental proof of the suggestion that in such Co(2)(II)Dy(2)(III)compounds two major relaxation pathways can be important in determining the overall magnetic behaviour of Co-II-4f systems.
机译:与我们先前报告的蝴蝶化合物相关的三种缺陷二耳协调簇,[CO2DY2(L)(4)(4)(2)(2)]中心点4thf(1)并配制为[CO2DY2(L)( 4)(NO 3)(2)(MeOH)(2)]中心点2CH(2)Cl(2)(2)(2),[CO2DY2(L)(4)(NO 3)(2)(DMF)(2))] 中心点2C(2)H(6)CO(3)和[Zn2Dy2(L)(4)(NO 3)(2)(2)(2)]中心点2CH(2)Cl(2)(4)是 合成和表征。 均显示典型的SMM行为,这是通过与中央3D离子协调的溶剂分子的性质引导。 (Zn2Dy2III)-DY-II,(4)提供了实验证据,其建议在这种CO(2)(II)DY(III)化合物中,两个主要的松弛途径在确定整体磁性行为方面都很重要 CO-II-4F系统。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号