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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Particle size effect on the superconducting properties of YBa2Cu3O7-x particles
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Particle size effect on the superconducting properties of YBa2Cu3O7-x particles

机译:粒度对YBA2Cu3O7-X颗粒的超导性能的影响

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摘要

YBCO samples with different microstructures were prepared after the thermal treatment of a precursor previously obtained by autocombustion. A drastic influence of the particle size on the magnetic behavior of the samples was observed. Thus, particles smaller than 110 nm do not exhibit superconducting properties and for those ranging around 200 nm the diamagnetic signal characteristic of the superconductivity at low temperature disappears in a large applied magnetic field. Particles larger than 300 nm do not exhibit the particle size effect. Accompanying such a phenomenon, an increase of the superconducting critical temperature is observed with the augmentation of the particle size, the lowest value being 18 K which corresponds to 110 nm particles.
机译:在通过自容量获得的前体的热处理后制备具有不同微结构的YBCO样品。 观察到粒度对样品的磁性行为的急剧影响。 因此,小于110nm的颗粒不表现出超导特性,并且对于大约200nm的那些,低温下的超导性的抗磁信号特性在大施加的磁场中消失。 大于300nm的颗粒不表现出粒度效应。 伴随这种现象,随着粒度的增强,观察到超导临界温度的增加,最低值为18 k,其对应于110nm颗粒。

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