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Synthesis of citric acid modified beta-cyclodextrin/activated carbon hybrid composite and their adsorption properties toward methylene blue

机译:将柠檬酸改性β-环糊精/活性炭杂化复合物的合成及其对亚甲基蓝的吸附性能

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摘要

In this article, citric acid modified beta-cyclodextrin/activated carbon hybrid (CA-beta-CD/AC) composites were synthesized by crosslinking reaction, and their adsorption properties for methylene blue were studied. The scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, and Brunauer-Emmett-Teller (BET) method were used to characterize the structure and the morphology of composite materials. It was investigated that the effect of experiment parameters on the adsorption performance including weight fraction of AC in the composite, the adsorbent dose, the initial concentration of MB, the solution pH value, contact time, and temperature. The maximum adsorption capacity calculated by the Langmuir isotherm is 862.07 mg g(-1). Kinetic studies show that the adsorption process follows the pseudo-first-order and pseud-second-order reaction models. Thermodynamic analysis indicated that the adsorption behavior was an exothermic reaction. (c) 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 48315.
机译:在本文中,通过交联反应合成柠檬酸改性的β-环糊精/活性炭杂化(CA-Beta-CD / AC)复合材料,研究了它们对亚甲基蓝的吸附性能。使用扫描电子显微镜(SEM),傅里叶变换红外(FTIR)光谱和Brunauer-Emmett-Teller(Bet)方法来表征复合材料的结构和形态。研究了实验参数对复合材料中AC的重量分数,吸附剂剂量,MB的初始浓度,溶液pH值,接触时间和温度的吸附性能的影响。 Langmuir等温线计算的最大吸附容量为862.07mg(-1)。动力学研究表明,吸附过程遵循伪一阶和伪二阶反应模型。热力学分析表明吸附行为是放热反应。 (c)2019 Wiley期刊,Inc.J.Phill。聚合物。 SCI。 2019,136,48315。

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  • 作者单位

    Qingdao Univ Coll Mech &

    Elect Engn State Key Lab Biofibers &

    Ecotext Qingdao 266071 Shandong Peoples R China;

    Qingdao Univ Coll Mech &

    Elect Engn State Key Lab Biofibers &

    Ecotext Qingdao 266071 Shandong Peoples R China;

    Qingdao Univ Coll Mech &

    Elect Engn State Key Lab Biofibers &

    Ecotext Qingdao 266071 Shandong Peoples R China;

    Qingdao Univ Coll Mech &

    Elect Engn State Key Lab Biofibers &

    Ecotext Qingdao 266071 Shandong Peoples R China;

    Qingdao Univ Coll Mech &

    Elect Engn State Key Lab Biofibers &

    Ecotext Qingdao 266071 Shandong Peoples R China;

    Qingdao Univ Coll Mech &

    Elect Engn State Key Lab Biofibers &

    Ecotext Qingdao 266071 Shandong Peoples R China;

    Qingdao Univ Coll Mech &

    Elect Engn State Key Lab Biofibers &

    Ecotext Qingdao 266071 Shandong Peoples R China;

    Qingdao Univ Coll Mech &

    Elect Engn State Key Lab Biofibers &

    Ecotext Qingdao 266071 Shandong Peoples R China;

    Qingdao Univ Coll Mech &

    Elect Engn State Key Lab Biofibers &

    Ecotext Qingdao 266071 Shandong Peoples R China;

    Qingdao Univ Coll Mech &

    Elect Engn State Key Lab Biofibers &

    Ecotext Qingdao 266071 Shandong Peoples R China;

    Qingdao Univ Coll Mech &

    Elect Engn State Key Lab Biofibers &

    Ecotext Qingdao 266071 Shandong Peoples R China;

    Qingdao Univ Coll Mech &

    Elect Engn State Key Lab Biofibers &

    Ecotext Qingdao 266071 Shandong Peoples R China;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 高分子化合物工业(高聚物工业);
  • 关键词

    activated carbon; adsorption; beta-cyclodextrin; citric acid; methylene blue;

    机译:活性炭;吸附;β-环糊精;柠檬酸;亚甲基蓝;

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