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Facile synthesis of a triptycene-based porous organic polymer with a high efficiency and recyclable adsorption for organic dyes

机译:基于三萜的多孔有机聚合物的容纳合成,具有高效率和可回收的有机染料吸附

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Water contamination resulting from organic dyes has had severe detrimental effects on human health and environmental tolerance. To address this issue, a delicate strategy for taking host-guest function in porous organic polymers via a facile Friedel-Crafts reaction of triptycene and post-modification was achieved. By means of this route, a sulfonic acid functionalized triptycene-based porous organic polymer (TPOP-SO3H) with a hierarchical structure and a desirable Brunauer-Emmett-Teller value of 1002 m(2)/g was synthesized this study. The TPOP-SO3H material demonstrated a maximum adsorption capacity for methylene blue of 97.1 mg/g. Remarkably, an absorption efficiency of more than 90% of TPOP-SO3H was observed even after five cycles. Therefore, such a hierarchical porous organic polymer can be highly recommended as one type of promising material for the treatment of organic dye-polluted wastewater. (c) 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2019, 136, 47987.
机译:由有机染料引起的水污染对人体健康和环境耐受性具有严重的不利影响。 为了解决这个问题,实现了通过平霉素和改性后的Friedel-Crafts在多孔有机聚合物中采取宿主 - 客户功能的微妙策略。 借助于该途径,磺酸官能化三氢化碳基多孔有机聚合物(TPOP-SO3H)具有分层结构和1002m(2)/ g的期望的Brunauer-Emmett-exculer值为1002m(2)/ g。 TPOP-SO3H材料证明了97.1mg / g的最大吸附能力。 值得注意的是,即使在五个循环后,也观察到超过90%的TPOP-SO3H的吸收效率。 因此,这种层级多孔有机聚合物可以强烈推荐为一种用于治疗有机染料污染废水的一种有希望的材料。 (c)2019 Wiley期刊,Inc.J.Phill。 聚合物。 SCI。 2019,136,47987。

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