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Cure characteristics, mechanical, thermal, and coloring properties of natural rubber/dye-loaded shell powder composites

机译:天然橡胶/染料壳粉末复合材料的固化特性,机械,热和着色性能

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摘要

To explore the application of shell powder (SP) in rubber, a dye-loaded SP (DSP) bio-filler based on SP and Congo red was incorporated into natural rubber (NR). The adsorption experiments demonstrated that the maximum monolayer adsorption capacity of Congo red onto SP was 69.3 mg/g. The effect of aluminate coupling agent and DSP was investigated by evaluating the cure characteristics, mechanical, thermal, and coloring properties of NR/DSP composites. It was suggested that the optimum amount of aluminate coupling agent was 2 wt %, and the best tensile strength (24.80 MPa) of vulcanizates was achieved at the DSP content of 20 phr, while other mechanical properties such as tear strength kept increasing with the addition of DSP. Furthermore, the improved thermal stability and uniform color distribution of the NR composites was obtained. The results indicate that DSP is promising to become a low-cost filler and pigment for rubber materials. (c) 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 45750.
机译:为了探讨壳体粉末(SP)在橡胶中的应用,将基于SP和刚果红色的染料加载的SP(DSP)生物填充物纳入天然橡胶(NR)中。吸附实验表明,刚果红色到SP上的最大单层吸附能力为69.3mg / g。通过评估NR / DSP复合材料的固化特性,机械,热和着色性能来研究铝酸盐偶联剂和DSP的效果。建议,铝酸盐偶联剂的最佳量为2wt%,并且在20phr的DSP含量下达到最佳拉伸强度(24.80MPa),而其他机械性能如撕裂强度随后保持增加DSP。此外,获得了Nr复合材料的改善的热稳定性和均匀的颜色分布。结果表明,DSP是有希望成为橡胶材料的低成本填料和颜料。 (c)2017 Wiley期刊,Inc.J.Phill。聚合物。 SCI。 2018,135,45750。

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