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Biowastes from wine as natural additive of polyolefins: Thermo- and photo-oxidation efficiency

机译:来自葡萄酒的生物母猪作为聚烯烃天然添加剂:热和光氧化效率

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摘要

Biowastes generated from agricultural industries constitute a new source for added value products that can be used in the polymer industry. Grape marc, a residue of the winery industry, is well-known to be a rich source of polyphenols. The present work reports the use of polyphenol cocktail extracted from black Pinot grape marc as natural antioxidant in polyolefins. The purpose is to advance in the field of green stabilizer, by using an innovating approach based on the direct use of an efficient cocktail rather than a single original molecule to stabilize polymer. The antioxidant efficiency of polyphenol cocktail is measured against photo- and thermo-oxidation conditions in the well-known polypropylene polyolefin. Attention is paid to molecular structure evolution by rheology, and the efficiency to delay oxidation by-product formation is monitored with infrared. The results confirm that cocktail approach is a promising route to develop green stabilizers. (c) 2018 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2018, 135, 46607.
机译:来自农业产业产生的生物母猪构成了可用于聚合物工业的附加值产品的新来源。葡萄马尔克是酒厂行业的残留物,是众所周知的是一种丰富的多酚来源。目前的工作报告使用从黑色卡皮葡萄Marc中提取的多酚鸡尾酒作为聚烯烃的天然抗氧化剂。目的是通过使用基于直接使用有效的鸡尾酒而不是单一原始分子来稳定聚合物的创新方法在绿色稳定剂领域。多酚鸡尾酒的抗氧化效率以众所周知的聚丙烯聚烯烃的光 - 和热氧化条件测量。通过流变学,注意分子结构演化,并用红外线监测延迟氧化副产物的效率。结果证实,鸡尾酒方法是开发绿色稳定剂的有希望的路线。 (c)2018 Wiley期刊,Inc.J.Phill。聚合物。 SCI。 2018,135,46607。

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