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Improved mechanical strength of p(AAm) interpenetrating hydrogel network due to microgranular cellulose embedding

机译:由于微粒纤维素嵌入而改善了P(AAM)互穿水凝胶网络的机械强度

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Here, polyacrylamide [p(AAm)]-based hydrogels were synthesized via redox polymerization technique in the presence of various amounts of microgranular cellulose (MGCell) such as 0, 10, 25, 50, 100, and 150 mg MGCell/g. The synthesized p(AAm)MGCell interpenetrating hydrogels were characterized spectroscopically by FTIR, thermally by TGA analysis, and mechanically via dynamic mechanical measurements. Furthermore, the effect of the amount of MGCell in p(AAm) hydrogels on swelling% (S%) degree and mechanical strength was investigated. It was found that the S% was decreased from 727 +/- 9 to 667 +/- 6, 642 +/- 8 and 619 +/- 10, 568 +/- 6 for p(AAm)-MGCell interpenetrating network hydrogels containing 10, 50, 100, and 150 mg MGCell, respectively. On the other hand, the Young modulus of p(AAm)-based hydrogels increased from 2.8 +/- 0.2 kPa to 3.1 +/- 0.03, 3.4 +/- 0.1, 3.6 +/- 0.3 and 4.3 +/- 0.3 kPa with the incorporation of 10, 50, 100, and 150 mg MGCell into p(AAm) hydrogels. (C) 2017 Wiley Periodicals, Inc.
机译:这里,通过氧化还原聚合技术在各种微粒纤维素(MgCell)如0,10,25,50,100和150mg MgCell / g存在下,通过氧化还原聚合技术合成基于丙烯酰胺的水凝胶。通过FTIR,通过TGA分析热,通过TGA分析,通过动态机械测量,通过FTIR进行光谱,通过FTIR进行光谱,通过动态机械测量来表征合成的P(AAM)Mgcell互穿水凝胶。此外,研究了MgCell在P(AAM)水凝胶中对溶胀%(S%)度和机械强度的影响。结果发现,对于P(AAM)-MGCELL互通网络水凝胶,S%从727 +/- 9至667 +/- 6,642 +/- 8和619 +/- 10,568 +/- 6减少分别为10,50,100和150mg mgcell。另一方面,基于2.8 +/- 0.2kPa至3.1 +/- 0.2kPa,3.4 +/- 0.1,3.6 +/- 0.3和4.3 +/- 0.3kPa的P(AAM)的杨氏模量增加将10,50,100和150mg mgcell掺入p(aam)水凝胶中。 (c)2017 Wiley期刊,Inc。

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