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Fabrication and characterization of carbon nanofibers from polyacrylonitrile/pitch blends

机译:聚丙烯腈/沥青混合物中碳纳米纤维的制造与表征

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摘要

Continuous carbon nanofibers had been widely studied based on different processing methods and precursors. Especially, electrospinning was introduced as a versatile method for fabricating ultrathin fibers. However, as the limitation of precursor, pitch had not been well studied due to its viscosity and miscibility problem. A comprehensive study on the electrospinning of the blends [pitch and polyacrylonitrile (PAN)] was explored. Thermodynamic miscibility was studied by using differential scanning calorimeter. Fourier transfer infrared spectroscopy was used to show interaction and potential reaction between pitch and PAN molecules. Finally, smooth, continuous, and cylindrical carbon nanofibers were successfully fabricated by electrospinning technique. Based on Raman analysis result, the addition of pitch enhanced the carbon crystallite which improved the overall electrical conductivity and modulus of nanofibers. (c) 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 45388.
机译:连续碳纳米纤维已被广泛研究基于不同的加工方法和前体。 特别是,将静电纺丝作为制造超薄纤维的通用方法。 然而,由于其粘度和混溶性问题,由于前体的限制而没有得到很好地研究。 探讨了对混合物静电纺丝的综合研究[沥青和聚丙烯腈(PAN)]。 通过使用差示扫描量热计研究了热力溶解性。 傅里叶转移红外光谱分析用于显示间距和平移分子之间的相互作用和潜在反应。 最后,通过静电纺丝技术成功地制造了光滑,连续和圆柱形碳纳米纤维。 基于拉曼分析结果,增强沥青增强的碳晶体,其提高了纳米纤维的总电导率和模量。 (c)2017 Wiley期刊,Inc.J.Phill。 聚合物。 SCI。 2017,134,45388。

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