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首页> 外文期刊>Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics >Powder sintered Ni-P/CNTs composites as three-dimensional self-supported efficient electrocatalysts for hydrogen evolution reaction
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Powder sintered Ni-P/CNTs composites as three-dimensional self-supported efficient electrocatalysts for hydrogen evolution reaction

机译:粉末烧结的Ni-P / CNTs复合材料作为氢进化反应的三维自支撑有效电催化剂

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摘要

Nickel phosphide can become a new generation of hydrogen evolution reaction (HER) non-precious catalyst due to the low price and abundant source. In this work, we reported the preparation of three-dimensional self-supported Ni-P/CHTs composite electrodes which adopted porous nickel powder and red phosphorus decorated with multi-walled carbon nanotubes by powder sintering. The phase, microstructure, and electrocatalytic performance of Ni-P/CHTs composite electrodes were systematically studied. The HER activity of Ni-P/CHTs composite electrodes could be affected by adjusting the molar ratio of Ni:P precursor. When the molar ratio of Ni:P was 1:1, the NiP-3 composite electrode has a better HER performance in acidic electrolyte than in alkaline electrolyte. This work indicates that the phase and micromorphology of the composite electrodes can be optimized by adjusting the Ni:P precursor molar ratio so that boosting the electrocatalytic HER performance. (C) 2020 Elsevier B.V. All rights reserved.
机译:磷化镍由于低价格和丰富的来源,磷化镍可成为新一代氢进化反应(她)非珍贵催化剂。在这项工作中,我们报道了通过粉末烧结用多孔镍粉和用多壁碳纳米管装饰的多孔镍粉和红磷的三维自支持的Ni-P / CHTS复合电极。系统地研究了Ni-P / CHTS复合电极的相位,微观结构和电催化性能。通过调节Ni:P前体的摩尔比来影响HI-P / CHTS复合电极的活性。当Ni:P的摩尔比为1:1时,NIP-3复合电极在酸性电解质中具有比碱性电解质更好的性能。该作品表明,通过调节Ni:P前体摩尔比可以优化复合电极的相位和微观术,从而提高了她的性能的电催化。 (c)2020 Elsevier B.v.保留所有权利。

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