Experimental and theoretical studies on electrocatalytic oxidation of arsenic (III) and iron (II) using chlorpromazine: Electrochemical and mechanistic study by digital simulation in liquid phase

Salimi Abdollah; Amini Nader; Naderi Kazhal; Ghafuori Houshiyar

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Experimental and theoretical studies on electrocatalytic oxidation of arsenic (III) and iron (II) using chlorpromazine: Electrochemical and mechanistic study by digital simulation in liquid phase

机译：使用氯丙嗪的砷（III）和铁（II）电催化氧化的实验与理论研究：用液相数字模拟电化学和机械研究

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The electrochemical properties of aqueous chlorpromazine (CPZ), at pH 2-8, were investigated by cyclic voltammetry at a boron doped diamond (BDD) electrode. The standard potential and kinetic parameters for CPZ were obtained by fitting experimental cyclic voltammograms to those generated by the DigSim program. The electrogenerated oxidized form of CPZ has been used as an efficient organic catalyst for the oxidation of As (III) and Fe (II) at BDD electrode immersed in aqueous media. The determination of catalytic rate constant (K-cat) was again accomplished by fitting experimental cyclic voltammograms with simulated ones. (C) 2017 Elsevier B.V. All rights reserved.

机译：通过环状伏安法在硼掺杂金刚石（BDD）电极下研究了氯丙嗪（CpZ）的电化学性质。 CPZ的标准电位和动力学参数是通过拟合实验循环伏型图，通过DIGSIM程序产生的那些。在浸入水性介质中的BDD电极，CPZ的CPZ的电化氧化形式已被用作氧化AS（III）和Fe（II）的有效有机催化剂。通过用模拟循环伏安图拟合实验循环伏安图再次实现催化速率常数（K-CAT）的测定。（c）2017年Elsevier B.V.保留所有权利。

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《Journal of Molecular Liquids》 |2017年第2017期|共6页
作者
Salimi Abdollah; Amini Nader; Naderi Kazhal; Ghafuori Houshiyar;
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作者单位

Univ Kurdistan Dept Chem Sanandaj 6617715175 Iran;

Kurdistan Univ Med Sci Environm Hlth Res Ctr Sanandaj Iran;

Kurdistan Univ Med Sci Vice Chancellor Food &

Drug Sanandaj Iran;

Kurdistan Univ Med Sci Liver &

Digest Res Ctr Sanandaj Iran;

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正文语种 eng
中图分类理论物理学;
关键词
Chlorpromazine hydrochloride (CPZ); As (III); Fe (II); Boron doped diamond electrode; DigSim; Simulation;

机译：盐酸氯丙嗪（CPZ）;AS（iii）;Fe（ii）;硼掺杂金刚石电极;DIGSIM;模拟;

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1. Experimental and theoretical studies on electrocatalytic oxidation of arsenic (III) and iron (II) using chlorpromazine: Electrochemical and mechanistic study by digital simulation in liquid phase [J] . Salimi Abdollah, Amini Nader, Naderi Kazhal, Journal of Molecular Liquids . 2017,第期

机译：使用氯丙嗪的砷（III）和铁（II）电催化氧化的实验与理论研究：用液相数字模拟电化学和机械研究
2. Mechanistic insights into cobalt(II/III)-catalyzed C-H oxidation: a combined theoretical and experimental study [J] . Guo Xiao-Kang, Zhang Lin-Bao, Wei Donghui, Chemical science . 2015,第12期

机译：钴（II / III）催化的C-H氧化的机理研究：理论与实验相结合的研究
3. Mechanistic insights into cobalt(II/III)-catalyzed C–H oxidation: a combined theoretical and experimental study [J] . Xiao-Kang Guo, Lin-Bao Zhang, Donghui Wei, Chemical science . 2015,第12期

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4. Kinetic modelling of microbial iron (II) oxidation, iron (III) hydrolysis, and arsenic (III) oxidation in acid waters [C] . K.M. Campbell, D.K. Nordstrom, M.B. Hay International Congress Arsenic In The Environment . 2012

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6. Mechanistic insights into cobalt(ii/iii)-catalyzed C–H oxidation: a combined theoretical and experimental study [O] . Xiao-Kang Guo, Lin-Bao Zhang, Donghui Wei, 2015

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8. Electrochemistry in Neutral Ambient-Temperature Ionic Liquids. 1. Studies of Iron (III), Neodymium (III), and Lithium(I) [R] . Lipsztajn, M., Osteryoung, R. A. 1985

机译：中性环境温度离子液体中的电化学。 1.铁（III），钕（III）和锂（I）的研究

Experimental and theoretical studies on electrocatalytic oxidation of arsenic (III) and iron (II) using chlorpromazine: Electrochemical and mechanistic study by digital simulation in liquid phase

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