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Float printing deposition to control the morphology of TiO2 photoanodes on woven textile metal substrates for TCO-free flexible dye-sensitized solar cells

机译:浮法印刷沉积以控制无纺布纺织金属衬底上的TiO2光电模块的形态,用于无铬柔性染料敏化太阳能电池

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摘要

The rapid growth of portable smart devices demands wearable energy sources that convert environmental energy into electricity. Textile based solar cells are one of the most promising candidates. In particular, the rapid development of fiber or textile structured dye sensitized solar cells gives us an optimistic prospect. However, the fundamental printing process for textile based substrates, which is far different from that of TCO coated flat substrates, and the optimized morphology necessary to obtain the best performance have not yet been studied systemically. In this study, a new deposition method called the floating printing method is developed to obtain the uniform and controllable deposition of electrode materials on textile or wire type substrates to be utilized in a paste printing process. In addition, FEM analysis was performed to observe the effect of morphologies on short circuit currents and find an optimized morphology for the best energy conversion efficiency. As a result, we have found that the electron source or diffusion path enhanced electron transportation with a thin wire-top region and that a distorting diffusion path degraded the short circuit current with a thick wire-top region. TCO-free flexible DSSCs cells were prepared utilizing a metal textile substrate, a paper spacer and Pt coated carbon counter electrodes, and obtained a 4.16% energy conversion efficiency. The results can be extended to a 3-dimensional analysis considering various textile substrates.
机译:便携式智能设备的快速增长要求将环境能量转化为电力的可穿戴能源。基于纺织的太阳能电池是最有前途的候选人之一。特别是,纤维或纺织结构染料敏化太阳能电池的快速发展为我们提供了乐观的前景。然而,迄今尚未全身研究纺织基材的基于纺织基材的基于纺织基材的根本印刷方法,以及获得最佳性能所需的优化形态。在该研究中,开发了一种新的沉积方法,以获得纺织品或线型衬底上的电极材料沉积的均匀和可控沉积,以便在糊状印刷过程中使用。此外,进行有限元分析以观察形态对短路电流的影响,并找到最佳能量转换效率的优化形态。结果,我们已经发现,电子源或扩散路径增强了具有细线区域的电子传输,并且扭曲的扩散路径利用厚的线顶区域降低了短路电流。利用金属纺织基板,纸张间隔物和PT涂覆的碳反对电极制备无菌柔性DSSCS细胞,得到4.16%的能量转换效率。考虑各种纺织基材,结果可以扩展到三维分析。

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  • 来源
    《RSC Advances》 |2016年第71期|共9页
  • 作者单位

    Korea Electrotechnol Res Inst Creat &

    Fundamental Res Div Nano Hybrid Technol Res Ctr Boolmosan Ro 10beon Gil Chang Won 641120 South Korea;

    Korea Electrotechnol Res Inst Creat &

    Fundamental Res Div Nano Hybrid Technol Res Ctr Boolmosan Ro 10beon Gil Chang Won 641120 South Korea;

    Korea Electrotechnol Res Inst Creat &

    Fundamental Res Div Nano Hybrid Technol Res Ctr Boolmosan Ro 10beon Gil Chang Won 641120 South Korea;

    Pusan Natl Univ Dept Organ Mat Sci &

    Engn 2 Busandaehak Ro 63beon Gil Busan 46241 South Korea;

    Korea Electrotechnol Res Inst Creat &

    Fundamental Res Div Nano Hybrid Technol Res Ctr Boolmosan Ro 10beon Gil Chang Won 641120 South Korea;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
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