Novel carbon nanofiber-supported Ni(0) nanoparticles catalyse the Heck reaction under ligand-free conditions

Zhu Ying; Bai Jie; Wang Junzhong; Li Chunping

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Novel carbon nanofiber-supported Ni(0) nanoparticles catalyse the Heck reaction under ligand-free conditions

机译：新型碳纳米纤维支撑的Ni（0）纳米颗粒催化在无配体条件下的静脉反应

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Nickel, as an inexpensive and abundant transition metal, is widely used in the field of catalysis. A novel one-dimensional carbon nanofiber-supported Ni(0) composite catalyst (Ni(0)/CNFs) was prepared in this work, and its catalytic properties in the Heck reaction were explored. Compared with conventional nickel-ligand catalyst systems, the solid Ni(0)/CNFs composite catalyst has unique advantages. Ni(0)/CNFs does not require ligands or complexes, which results in high efficiency and is beneficial for reuse in the Heck reaction.

机译：镍作为廉价且丰富的过渡金属，广泛用于催化领域。在该工作中制备了一种新型一维碳纳米纤维负载的Ni（0）复合催化剂（Ni（0）/ CNF），探讨了其在Heck反应中的催化性质。与常规镍 - 配体催化剂体系相比，固体Ni（0）/ CNFS复合催化剂具有独特的优点。 Ni（0）/ CNFS不需要配体或复合物，这导致高效率，并且有利于重用在Heck反应中。

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《RSC Advances》 |2016年第35期|共4页
作者
Zhu Ying; Bai Jie; Wang Junzhong; Li Chunping;
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Inner Mongolia Univ Technol Chem Engn Coll Hohhot 010051 Peoples R China;

Inner Mongolia Univ Technol Chem Engn Coll Hohhot 010051 Peoples R China;

Inner Mongolia Univ Technol Chem Engn Coll Hohhot 010051 Peoples R China;

Inner Mongolia Univ Technol Chem Engn Coll Hohhot 010051 Peoples R China;

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正文语种 eng
中图分类化学;
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1. Novel carbon nanofiber-supported Ni(0) nanoparticles catalyse the Heck reaction under ligand-free conditions [J] . Zhu Ying, Bai Jie, Wang Junzhong, RSC Advances . 2016,第35期

机译：新型碳纳米纤维支撑的Ni（0）纳米颗粒催化在无配体条件下的静脉反应
2. Carbon nanofiber-supported palladium nanoparticles as potential recyclable catalysts for the Heck reaction [J] . Jun Zhu, Jinghong Zhou, Tiejun Zhao Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications . 2009,第1a2期

机译：碳纳米纤维负载的钯纳米粒子可作为Heck反应的潜在可回收催化剂
3. Palladium immobilized on Fe3O4/ZnO nanoparticles: a novel magnetically recyclable catalyst for Suzuki-Miyaura and heck reactions under ligand-free conditions [J] . Hosseini-Sarvari Mona, Khanivar Ameneh, Moeini Fatemeh Journal of the Iranian Chemical Society . 2016,第1期

机译：固定在Fe3O4 / ZnO纳米颗粒上的钯：铃木宫浦和在无配体条件下的heck反应的新型可磁循环催化剂
4. Ligand-Free and Regioselectivity of the Heck Reaction Catalyzed by Pd(0) Nanoparticles at Ambient Conditions under Ultrasonic Irradiation [C] . Yanhua Zhang, Eyu Ji, Songtao Chen, EMEM 2010;International conference of environment materials and environment management . 2010

机译：Pd（0）纳米粒子在环境条件下超声辐射催化的Heck反应的无配体和区域选择性
5. Les reactions de couplage carbone-carbone en beta-arylation de type Heck pallado-catalysees par des catalyseurs heterogenes mesoporeux. [D] . Ngwem, Cyril Ivan. 2009

机译：非均相介孔催化剂催化的Heck型Palladoβ-芳基化中的碳-碳偶联反应。
6. Carbon-Carbon Cross Coupling Reactions in Ionic Liquids Catalysed by Palladium Metal Nanoparticles [O] . Martin H. G. Prechtl, Jackson D. Scholten, Jairton Dupont 2010

机译：钯金属纳米粒子催化的离子液体中碳-碳交叉偶联反应
7. Ligand-free palladium catalysed Heck reaction of methyl 2-acetamido acrylate and aryl bromides as key step in the synthesis of enantiopure substituted phenylalanines [O] . Willans, Charlotte E., Mulders, Jan M.C.A., Vries, Johannes G. de, 2003

机译：无配体钯催化的2-乙酰氨基丙烯酸甲酯和芳基溴化物的Heck反应是对映体取代的苯丙氨酸合成的关键步骤

Novel carbon nanofiber-supported Ni(0) nanoparticles catalyse the Heck reaction under ligand-free conditions

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