A study of oligothiophene-acceptor dyes in p-type dye-sensitized solar cells

Sheibani Esmaeil; Zhang Lei; Liu Peng; Xu Bo; Mijangos Edgar; Boschloo Gerrit; Hagfeldt Anders; Hammarstrom Leif; Kloo Lars; Tian Haining

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A study of oligothiophene-acceptor dyes in p-type dye-sensitized solar cells

机译：p型染料敏化太阳能电池中低噻吩接受染料的研究

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Two new dyes, E1 and E2, equipped with triphenylamine as the electron donor, oligothiophene as the linker and different electron acceptor groups, have been designed and synthesized as photosensitizers for p-type dye-sensitized solar cells (p-DSCs). A systematic study of the effect of molecular structures on the observed photophysical properties, the electron/hole recombination process, the overall performance and the interfacial charge separation was carried out. Transient absorption spectroscopy (TAS) shows that the E1 dye with a napthoilene-1,2-benzimidazole (NBI) unit as the acceptor has a longer lifetime in the reduced state than the E2 dye with a malononitrile subunit on the NiO surface.

机译：两种新的染料，E1和E2配备了作为电子给体，低噻吩作为接头和不同电子受体基团的三苯胺，已经设计和合成为P型染料敏化太阳能电池（P-DSC）的光敏剂。进行了分子结构对观察到的光学性质，电子/空穴重组过程，整体性能和界面电荷分离的影响的系统研究。瞬态吸收光谱（TAs）表明，作为受体的萘基亚烯-1,2-苯并咪唑（NBI）单元的E1染料在降低状态下具有比NIO表面上的丙二腈亚基的E2染料在降低的状态下具有更长的寿命。

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来源
《RSC Advances》 |2016年第22期|共13页
作者
Sheibani Esmaeil; Zhang Lei; Liu Peng; Xu Bo; Mijangos Edgar; Boschloo Gerrit; Hagfeldt Anders; Hammarstrom Leif; Kloo Lars; Tian Haining;
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KTH Royal Inst Technol Dept Chem Chem Sci &

Engn Organ Chem SE-10044 Stockholm Sweden;

Uppsala Univ Dept Chem Angstrom Lab Phys Chem Box 523 SE-75120 Uppsala Sweden;

KTH Royal Inst Technol Sch Chem Sci &

Engn Dept Chem Appl Phys Chem Tekn Ringen 30 SE-10044 Stockholm Sweden;

KTH Royal Inst Technol Dept Chem Chem Sci &

Engn Organ Chem SE-10044 Stockholm Sweden;

Uppsala Univ Dept Chem Angstrom Lab Phys Chem Box 523 SE-75120 Uppsala Sweden;

Uppsala Univ Dept Chem Angstrom Lab Phys Chem Box 523 SE-75120 Uppsala Sweden;

Uppsala Univ Dept Chem Angstrom Lab Phys Chem Box 523 SE-75120 Uppsala Sweden;

Uppsala Univ Dept Chem Angstrom Lab Phys Chem Box 523 SE-75120 Uppsala Sweden;

KTH Royal Inst Technol Sch Chem Sci &

Engn Dept Chem Appl Phys Chem Tekn Ringen 30 SE-10044 Stockholm Sweden;

KTH Royal Inst Technol Dept Chem Chem Sci &

Engn Organ Chem SE-10044 Stockholm Sweden;

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正文语种 eng
中图分类化学;
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1. A study of oligothiophene-acceptor dyes in p-type dye-sensitized solar cells [J] . Sheibani Esmaeil, Zhang Lei, Liu Peng, RSC Advances . 2016,第22期

机译：p型染料敏化太阳能电池中低噻吩接受染料的研究
2. Effect of auxiliary group for p-type organic dyes in NiO-based dye-sensitized solar cells: The first principal study [J] . Li Juan, Zhang Shijie, Shao Di, Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy . 2018,第期

机译：P型有机染料辅助基团在基于NIO的染料敏化太阳能电池中的影响：第一个主要研究
3. Comparative study on the interactions of sulfide and iodine mediators with a dye in p-type dye-sensitized solar cells [J] . Kusama Hitoshi Journal of Photochemistry and Photobiology, A. Chemistry . 2018,第期

机译：硫化物和碘介质与染料在p型染料敏化太阳能电池中的相互作用的比较研究
4. Cathodic sensitization for p-type dye-sensitized solar cells: our recent progresses in dyes, semiconductors and device physics [C] . Zhiqiang Ji, Mingzhe Yu, Gayatri Natu ACS National Meeting and Exhibition . 2013

机译：P型染料敏化太阳能电池的阴极致敏：我们最近在染料，半导体和器件物理学进展
5. Spectroscopic and photoelectrochemical studies of metal-free dyes for applications in dye-sensitized solar cells. [D] . Mulhern, Kacie Ryan. 2013

机译：用于染料敏化太阳能电池的无金属染料的光谱和光电化学研究。
6. Assembly charge-transfer and solar cell performance with porphyrin-C60 on NiO for p-type dye-sensitized solar cells [O] . Elisabetta Benazzi, Gareth H. Summers, Fiona A. Black, -1

机译：P型染料敏化太阳能电池的卟啉-C60对卟啉-C60的组装电荷转移和太阳能电池性能
7. Improved conversion efficiency of 10 for solid-state dye-sensitized solar cells utilizing P-type semiconducting CuI and multi-dye consisting of novel porphyrin dimer and organic dyes [O] . Naohiko Kato, Shinya Moribe, Masahito Shiozawa, 2018

机译：利用新型卟啉二聚体和有机染料组成的P型半导体Cui和多染料，改善固态染料敏化太阳能电池的转化效率为10％

A study of oligothiophene-acceptor dyes in p-type dye-sensitized solar cells

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