Enhancement of peroxidase-like activity of N-doped graphene assembled with iron-tetrapyridylporphyrin

Magerusan L.; Socaci C.; Pogacean F.; Rosu M. -C.; Biris A. R.; Coros M.; Turza A.; Floare-Avram V.; Katona G.; Pruneanu S.

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Enhancement of peroxidase-like activity of N-doped graphene assembled with iron-tetrapyridylporphyrin

机译：用铁 - 四吡啶氨酸组装的N掺杂石墨烯的过氧化物酶样活性的增强

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The paper describes two preparation methods for the non-covalent functionalization of N-doped graphene with iron(III)-tetrapyridylporphyrin. The obtained nanomaterials show enhanced peroxidase-like activity compared to N-doped graphene and effectively oxidize 3,3'-dimethylbenzidine with hydrogen peroxide with the formation of a blue product. The catalytic activity and implicitly the color intensity are dependent on the hydrogen peroxide concentration, thus creating the possibility for its quantification by UV-Vis spectroscopy. In addition, the nanomaterial obtained by direct functionalization was investigated for its catalytic ability to remove bisphenol A from pH neutral water solutions.

机译：本文描述了具有铁（III）-Tetrapyridylylin的N-掺杂石墨烯的非共价官能化的两种制备方法。与N掺杂的石墨烯相比，所得纳米材料显示出增强的过氧化物酶样活性，并有效地将3,3'-二甲基苯胺与过氧化氢，形成蓝产物。催化活性和隐含的颜色强度取决于过氧化氢浓度，从而产生通过UV-Vis光谱法的定量的可能性。另外，研究了通过直接官能化获得的纳米材料以催化能力除去来自pH中性水溶液的双酚A.

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来源
《RSC Advances》 |2016年第83期|共10页
作者
Magerusan L.; Socaci C.; Pogacean F.; Rosu M. -C.; Biris A. R.; Coros M.; Turza A.; Floare-Avram V.; Katona G.; Pruneanu S.;
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作者单位

Natl Inst Res &

Dev Isotop &

Mol Technol 67-103 Donat Cluj Napoca 400293 Romania;

Natl Inst Res &

Dev Isotop &

Mol Technol 67-103 Donat Cluj Napoca 400293 Romania;

Natl Inst Res &

Dev Isotop &

Mol Technol 67-103 Donat Cluj Napoca 400293 Romania;

Natl Inst Res &

Dev Isotop &

Mol Technol 67-103 Donat Cluj Napoca 400293 Romania;

Natl Inst Res &

Dev Isotop &

Mol Technol 67-103 Donat Cluj Napoca 400293 Romania;

Natl Inst Res &

Dev Isotop &

Mol Technol 67-103 Donat Cluj Napoca 400293 Romania;

Natl Inst Res &

Dev Isotop &

Mol Technol 67-103 Donat Cluj Napoca 400293 Romania;

Natl Inst Res &

Dev Isotop &

Mol Technol 67-103 Donat Cluj Napoca 400293 Romania;

Univ Babes Bolyai Fac Chem &

Chem Engn Arany Janos 11 Cluj Napoca Romania;

Natl Inst Res &

Dev Isotop &

Mol Technol 67-103 Donat Cluj Napoca 400293 Romania;

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1. Enhancement of peroxidase-like activity of N-doped graphene assembled with iron-tetrapyridylporphyrin [J] . Magerusan L., Socaci C., Pogacean F., RSC Advances . 2016,第83期

机译：用铁 - 四吡啶氨酸组装的N掺杂石墨烯的过氧化物酶样活性的增强
2. Enhanced peroxidase-like activity of hierarchical MoS2-decorated N-doped carbon nanotubes with synergetic effect for colorimetric detection of H2O2 and ascorbic acid [J] . Jing Zheng, Dandan Song, Hong Chen, 中国化学快报（英文版） . 2020,第005期

机译：增强了分层MOS2装饰的N掺杂的N掺杂碳纳米管的过氧化物酶样活性，具有同学检测H2O2和抗坏血酸的同学效果
3. CuO/WO_3 nanoparticles decorated graphene oxide nanosheets with enhanced peroxidase-like activity for electrochemical cancer cell detection and targeted therapeutics [J] . Alizadeh Negar, Salimi Abdollah, Hallaj Rahman, Materials science & engineering . 2019,第JUNa期

机译：具有增强的过氧化物酶样活性的CuO / WO_3纳米颗粒装饰的氧化石墨烯纳米片用于电化学癌细胞检测和靶向治疗
4. Ammonia Oxidation Activity Enhancement of Platinum with N-Doped Graphene and Tungsten Carbide Support [C] . Kumar Siddharth, Minhua Shao Pacific Rim Meeting on Electrochemical and Solid-State Science . 2020

机译：用N掺杂石墨烯和碳化钨载铂氧化活性增强
5. Ultrafast electronic dynamics in unipolar n-doped indium gallium arsenide/gallium arsenide self-assembled quantum dots. [D] . Wu, Zong-Kwei J. 2006

机译：单极n掺杂砷化铟镓/砷化镓自组装量子点中的超快电子动力学。
6. Synergistically Enhanced Electrocatalytic Performanceof an N-Doped Graphene Quantum Dot-Decorated 3D MoS2–Graphene Nanohybrid for Oxygen Reduction Reaction [O] . Ramalingam Vinoth, IndrajitM. Patil, Alagarsamy Pandikumar, 2016

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7. N-Doped Graphene-Decorated NiCo Alloy Coupled with Mesoporous NiCoMoO Nano-sheet Heterojunction for Enhanced Water Electrolysis Activity at High Current Density [O] . Guangfu Qian, Jinli Chen, Tianqi Yu, 2021

机译：N-掺杂的石墨烯装饰的Nico合金与中孔尼古罗纳米片异质结合，用于高电流密度的增强水电解活动

Enhancement of peroxidase-like activity of N-doped graphene assembled with iron-tetrapyridylporphyrin

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