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Thin-walled graphitic nanocages with nitrogen-doping as superior performance anodes for lithium-ion batteries

机译:具有氮气掺杂的薄壁石墨纳米物作为锂离子电池的优异性能阳极

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摘要

N-Doped nanocages with thin-walled graphitic shells (similar to 1.2 nm) were synthesized by removing the ferrous cores of Fe@C nanoparticles. The Fe@C nanopores were prepared by floating catalytic pyrolysis with the N atoms being in situ doped in their graphitic shells. Due to the thin-walled graphitic shells of the nanocages, the fast distribution of the electrolyte and ions was achieved and the prepared nanocage-based anode of lithium-ion batteries showed excellent performance: a high reversible specific capacity (after 50 cycles; 760 mA h g (1) at 0.5 A g (1)) and a remarkable rate capability (after 40 cycles; 250 mA h g (-1) at 10 A g (-1)).
机译:通过除去Fe @ C纳米颗粒的黑色金属芯来合成具有薄壁石墨壳(类似于1.2nm)的N掺杂的纳米分析。 通过漂浮在其石墨壳中的N原子掺杂N原子掺杂催化热解来制备Fe @ C纳米孔。 由于纳米病的薄壁石墨壳,实现了电解质和离子的快速分布,并且锂离子电池的制备的纳米载体阳极显示出优异的性能:高可逆的特定容量(50次循环后; 760 mA Hg(1)在0.5 a g(1))和显着的速率能力(在40次循环后; 250 mA hg(-1),10 a g(-1))。

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  • 来源
    《RSC Advances》 |2016年第65期|共4页
  • 作者单位

    Shanghai Inst Technol Sch Mat Sci &

    Engn Shanghai 201418 Peoples R China;

    Shanghai Inst Technol Sch Mat Sci &

    Engn Shanghai 201418 Peoples R China;

    Shanghai Inst Technol Sch Mat Sci &

    Engn Shanghai 201418 Peoples R China;

    Shanghai Inst Technol Sch Mat Sci &

    Engn Shanghai 201418 Peoples R China;

    Shanghai Inst Technol Sch Mat Sci &

    Engn Shanghai 201418 Peoples R China;

    Shanghai Inst Technol Sch Mat Sci &

    Engn Shanghai 201418 Peoples R China;

    Shanghai Inst Technol Sch Mat Sci &

    Engn Shanghai 201418 Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

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