Ctr-1 Mets7 motif inspiring new peptide ligands for Cu(I)-catalyzed asymmetric Henry reactions under green conditions

Pellegrino Sara; Facchetti Giorgio; Contini Alessandro; Gelmi Maria Luisa; Erba Emanuela; Gandolfi Raffaella; Rimoldi Isabella

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Ctr-1 Mets7 motif inspiring new peptide ligands for Cu(I)-catalyzed asymmetric Henry reactions under green conditions

机译：CTR-1 METS7 MOTIF激发CU（I）的新肽配体 - 在绿色条件下催化不对称亨利反应

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Taking inspiration from the Ctr-1 Mets7 Cu(I) binding motif, effective hybrid catalysts have been developed for asymmetric Henry condensations under green conditions. The introduction of an unnatural dipeptide mimic allowed to increase the catalytic performance. Metal transporters' binding domains could be exploited as a strategy for designing hybrid catalysts for homogeneous catalysis.

机译：从CTR-1 METS7 Cu（I）结合基质中，已经开发了在绿色条件下为不对称亨利缩合而开发了有效的杂交催化剂。引入非自然二肽模仿允许增加催化性能。金属转运蛋白的结合结构域可以被利用作为设计杂种催化剂的均匀催化剂的策略。

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来源
《RSC Advances》 |2016年第75期|共5页
作者
Pellegrino Sara; Facchetti Giorgio; Contini Alessandro; Gelmi Maria Luisa; Erba Emanuela; Gandolfi Raffaella; Rimoldi Isabella;
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Univ Milan Dipartimento Sci Farmaceut Via Venezian 21 I-20133 Milan Italy;

Univ Milan Dipartimento Sci Farmaceut Via Venezian 21 I-20133 Milan Italy;

Univ Milan Dipartimento Sci Farmaceut Via Venezian 21 I-20133 Milan Italy;

Univ Milan Dipartimento Sci Farmaceut Via Venezian 21 I-20133 Milan Italy;

Univ Milan Dipartimento Sci Farmaceut Via Venezian 21 I-20133 Milan Italy;

Univ Milan Dipartimento Sci Farmaceut Via Venezian 21 I-20133 Milan Italy;

Univ Milan Dipartimento Sci Farmaceut Via Venezian 21 I-20133 Milan Italy;

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正文语种 eng
中图分类化学;
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专利

1. Ctr-1 Mets7 motif inspiring new peptide ligands for Cu(I)-catalyzed asymmetric Henry reactions under green conditions [J] . Pellegrino Sara, Facchetti Giorgio, Contini Alessandro, RSC Advances . 2016,第75期

机译：CTR-1 METS7 MOTIF激发CU（I）的新肽配体 - 在绿色条件下催化不对称亨利反应
2. Modular bipyridine ligands coupled with Cinchona alkaloids for Cu(II)-catalyzed asymmetric Henry reactions [J] . Liu M., Ma S., Tian Z., Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2013,第12期

机译：模块化联吡啶配体与金鸡纳生物碱偶联用于铜（II）催化的不对称亨利反应
3. Pyrrole macrocyclic ligands for Cu-catalyzed asymmetric henry reactions [J] . Gualandi A., Cerisoli L., Stoeckli-Evans H., The Journal of Organic Chemistry . 2011,第9期

机译：铜催化的不对称亨利反应的吡咯大环配体
4. SYNTHESIS OF 2-(2'-PIPERIDNYL)PYRIDINE DERIVATIVES AND THEIR USE AS LIGANDS IN ASYMMETRIC HENRY AND AZA-HENRY REACTIONS [C] . Artur Noole, Tonis Kanger European Symposium on Organic Chemistry . 2009

机译：合成2-（2'-哌啶基）吡啶衍生物及其用作不对称亨利和AZA-HENRY反应中的配体的用途
5. I. Heterogeneous cross-coupling reactions catalyzed by nickel-in-charcoal and copper-in-charcoal. II. Asymmetric 1,2/1,4-reductions catalyzed by copper hydride. III. Atropselective synthesis of the biaryl A-B ring system of vancomycin utilizing an internally tethered, nonracemic ligand. [D] . Lee, Ching-Tien. 2009

机译：I.炭中镍和炭中铜催化的非均相交叉偶联反应。二。氢化铜催化的不对称1,2 / 1,4-还原反应。三，利用内部束缚的非外消旋配体进行万古霉素联芳基A-B环系统的选择性催化合成。
6. Cu (II)-Catalyzed Asymmetric Henry Reaction with a Novel C1-Symmetric Aminopinane-Derived Ligand [O] . Liudmila Filippova, Yngve Stenstrøm, Trond Vidar Hansen 2015

机译：铜（II）催化的不对称亨利反应与新型的C1对称氨基pin烷衍生的配体
7. Cu (II)-Catalyzed Asymmetric Henry Reaction with a Novel C1-Symmetric Aminopinane-Derived Ligand [O] . Liudmila Filippova, Yngve Stenstrøm, Trond Vidar Hansen 2015

机译：Cu（II）催化的不对称亨利反应与新型C1对称氨基嘌呤衍生的配体

Ctr-1 Mets7 motif inspiring new peptide ligands for Cu(I)-catalyzed asymmetric Henry reactions under green conditions

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