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Tailoring the optical properties of ZnO nano-layers and their effect on in vitro biocompatibility

机译:剪裁ZnO纳米层的光学性质及其对体外生物相容性的影响

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This paper highlights the use of Al2O3 and SnO2 films as protecting layers to tailor the optical properties and biocompatibility of ZnO nano-films. ZnO, ZnO/Al2O3 and ZnO/SnO2 nano-films have been deposited inside 3-dimensional (3D) structures such as anodic aluminium oxide (AAO) membranes via a gas phase atomic layer deposition (ALD) process. We show that ZnO/Al2O3 multilayers exhibit improved excitonic photoluminescence properties compared to ZnO only, whereas ZnO/SnO2 multilayers quench the near band edge emission signal. In addition, in vitro experiments on Caco-2/TC7 cells and Vibrio fischeri bacteria reveal that ZnO/Al2O3 and ZnO/SnO2 multilayers display enhanced biocompatibility in liquid media compared to ZnO. We attribute the improvement of the biocompatibility to a lower dissolution of the ZnO nano-film when protected by Al2O3 or SnO2.
机译:本文突出了使用Al2O3和SnO2薄膜作为保护层,以定制ZnO纳米膜的光学性质和生物相容性。 通过气相原子层沉积(ALD)工艺,ZnO,ZnO / Al2O3和ZnO / SnO2纳米膜沉积在三维(3D)结构之外,例如阳极氧化铝(AaO)膜。 我们表明,与ZnO相比,ZnO / Al2O3多层表现出改善的激发致光致发光性能,而ZnO / SnO2多层淬火近带边缘发射信号。 此外,在Caco-2 / TC7细胞和vibrioFischeri细菌上的体外实验表明,与ZnO相比,ZnO / Al2O3和ZnO / SnO 2多层显示液体介质中的生物相容性增强。 当受Al 2 O 3或SnO 2保护时,我们将生物相容性的改善归因于ZnO纳米膜的较低溶解。

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