TsOH-mediated reaction of aziridinofullerene with diols for the preparation of fullerene-fused dioxygenated ring compounds

Wu Jun; Li Fa-Bao; Zhang Xiao-Feng; Shi Ji-Long; Liu Li

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TsOH-mediated reaction of aziridinofullerene with diols for the preparation of fullerene-fused dioxygenated ring compounds

机译：Tsoh介导的氮素酸氢烯烃与二醇制备富勒烯 - 稠合的二氧化环化合物的反应

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The double nucleophilic substitution reaction of aziridinofullerene with diols in the presence of p-toluenesulfonic acid affords a series of rare fullerene-fused dioxygenated ring compounds with six- to ten-membered heterocycles. A possible reaction mechanism for product formation is proposed.

机译：氮素酸氢脲与二醇在对甲苯磺酸存在下的双亲核取代反应得到一系列稀有富勒烯 - 熔融二氧化的环化合物，其具有六〜10元杂环。提出了一种可能的产物形成反应机制。

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《RSC Advances》 |2015年第39期|共6页
作者
Wu Jun; Li Fa-Bao; Zhang Xiao-Feng; Shi Ji-Long; Liu Li;
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作者单位

Hubei Univ Hubei Collaborat Innovat Ctr Adv Organ Chem Mat Sch Chem &

Chem Engn Key Lab Synth &

Applicat Organ Funct Mol Minist E Wuhan 430062 Peoples R China;

Hubei Univ Hubei Collaborat Innovat Ctr Adv Organ Chem Mat Sch Chem &

Chem Engn Key Lab Synth &

Applicat Organ Funct Mol Minist E Wuhan 430062 Peoples R China;

Hubei Univ Hubei Collaborat Innovat Ctr Adv Organ Chem Mat Sch Chem &

Chem Engn Key Lab Synth &

Applicat Organ Funct Mol Minist E Wuhan 430062 Peoples R China;

Hubei Univ Hubei Collaborat Innovat Ctr Adv Organ Chem Mat Sch Chem &

Chem Engn Key Lab Synth &

Applicat Organ Funct Mol Minist E Wuhan 430062 Peoples R China;

Hubei Univ Hubei Collaborat Innovat Ctr Adv Organ Chem Mat Sch Chem &

Chem Engn Key Lab Synth &

Applicat Organ Funct Mol Minist E Wuhan 430062 Peoples R China;

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正文语种 eng
中图分类化学;
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1. TsOH-mediated reaction of aziridinofullerene with diols for the preparation of fullerene-fused dioxygenated ring compounds [J] . Wu Jun, Li Fa-Bao, Zhang Xiao-Feng, RSC Advances . 2015,第39期

机译：Tsoh介导的氮素酸氢烯烃与二醇制备富勒烯 - 稠合的二氧化环化合物的反应
2. Synthesis of Fullerene-Fused Dioxanes/Dioxepanes: Ferric Perchlorate-Mediated One-Step Reaction of [60]Fullerene with Diols [J] . Zhang Xiao-Feng, Li Fa-Bao, Wu Jun, The Journal of Organic Chemistry . 2015,第12期

机译：富勒烯熔融的二恶烷/二恶庚烷的合成：高氯酸铁介导的[60]富勒烯与二醇的一步反应
3. Lewis Base-Catalyzed Reaction of Aziridinofullerene with Ureas for the Preparation of Fulleroimidazolidinones [J] . Xing Meng-Lei, Lu Xin-Wei, Miao Chun-Bao, The Journal of Organic Chemistry . 2014,第23期

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4. Creation of Carbon Five-Membered Ring Compounds by Hydrothermal Reaction under Mild Conditions and Their Application to High Value Compounds [C] . Takaaki Kamishima, Toshihiro Watanabe, Yoshitaka Koseki 日本化学会春季年会講演予稿集 . 2018

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5. Modified Nazarov reactions and ring expansion chemistry: Useful methodologies for the construction of carbocyclic and heterocyclic compounds. [D] . Grant, Tina Nicola. 2008

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6. Successive C-C Coupling of Dienes to Vicinally Dioxygenated Hydrocarbons: Ruthenium Catalyzed 4+2 Cycloaddition across the Diol Hydroxycarbonyl or Dione Oxidation Levels [O] . Laina M. Geary, Ben W. Glasspoole, Mary M. Kim, -1

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TsOH-mediated reaction of aziridinofullerene with diols for the preparation of fullerene-fused dioxygenated ring compounds

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