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Preparation of beta-cyclodextrin functionalized reduced graphene oxide: application for electrochemical determination of paracetamol

机译:β-环糊精的制备官能化的还原石墨烯氧化物:用于扑热氨基酚的电化学测定的应用

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摘要

beta-Cyclodextrin functionalized reduced graphene oxide (beta-CD/RGO) was successfully prepared using a simple wet chemical method. The beta-CD/RGO nanohybrid was characterized by UV-vis spectroscopy, FTIR, Raman spectroscopy, TEM and SEM. The results confirmed that beta-CD had effectively covered the RGO surface. The beta-CD/RGO nanohybrid modified glassy carbon electrode was employed for the sensitive electrochemical determination of paracetamol. Cyclic voltammetry measurements indicated that beta-CD/RGO could significantly enhance the electrochemical response of paracetamol due to the outstanding electronic properties of RGO sheets and the high supramolecular recognition and enrichment capability of beta-CD. The experimental factors were investigated and optimized. Under optimized conditions, the amperometric oxidation currents of paracetamol were linearly proportional to the concentration in the range of 0.01 to 0.8 mM with a detection limit of 2.3 mu M (S/N = 3). Furthermore, the proposed sensor exhibited an excellent anti-interference property and acceptable reproducibility.
机译:β-环糊精官能化还原氧化石墨烯(β-CD / RGO)使用简单的湿化学方法成功地制备。贝塔-CD / RGO纳米杂化物的特点是紫外可见光谱,红外光谱,拉曼光谱,TEM和SEM。结果证实,测试-CD已经有效覆盖了RGO表面。所述β-CD / RGO纳米杂化物修饰的玻碳电极用于该敏感电化学确定对乙酰氨基酚。循环伏安测量表明,测试版,CD / RGO能显著提高对乙酰氨基酚的电化学反应,由于RGO张优秀的电子特性和高超分子识别和β-CD的铀浓缩能力。实验因素进行了研究和优化。在优化条件下,对乙酰氨基酚的安培计氧化电流是成线性比例在0.01至0.8 mM的浓度为2.3微米(S / N = 3)的检测极限。此外,所提出的传感器表现出优异的抗干扰性能和可接受的再现性。

著录项

  • 来源
    《RSC Advances》 |2015年第94期|共6页
  • 作者

    Fu Li; Lai Guosong; Yu Aimin;

  • 作者单位

    Swinburne Univ Technol Fac Sci Engn &

    Technol Dept Chem &

    Biotechnol Hawthorn Vic 3122 Australia;

    Hubei Normal Univ Dept Chem Hubei Collaborat Innovat Ctr Rare Met Chem Hubei Key Lab Pollutant Anal &

    Reuse Technol Huangshi 435002 Peoples R China;

    Swinburne Univ Technol Fac Sci Engn &

    Technol Dept Chem &

    Biotechnol Hawthorn Vic 3122 Australia;

  • 收录信息
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

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