Perfluorobutyl iodide-assisted direct cyanomethylation of azoles and phenols with acetonitrile

Zhang Juan; Wu Wei; Ji Xinfei; Cao Song

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Perfluorobutyl iodide-assisted direct cyanomethylation of azoles and phenols with acetonitrile

机译：用乙腈的全氟丁基碘辅助直接氰基甲基化和苯酚

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A perfluorobutyl iodide-assisted transition-metal-free cyanomethylation of azoles and phenols with acetonitrile in the presence of NaH has been developed. The reaction proceeded smoothly under mild reaction conditions to give the cyanomethylated products in moderate to high yields. A mechanism involving the cyanomethyl radical through C-H bond cleavage in acetonitrile was proposed.

机译：已经开发出NaH存在下吡酰碘化物辅助β和含有乙腈的苯酚的全氟丁基碘化物 - 无金属 - 甲基化。在温和的反应条件下，反应平稳地进行，使氰基甲基化产物中等至高收率。提出了一种涉及乙腈中的乙二甲基的机制通过C-H键在乙腈中的裂解。

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来源
《RSC Advances》 |2015年第26期|共4页
作者
Zhang Juan; Wu Wei; Ji Xinfei; Cao Song;
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作者单位

E China Univ Sci &

Technol Sch Pharm Shanghai Key Lab Chem Biol Shanghai 200237 Peoples R China;

E China Univ Sci &

Technol Sch Pharm Shanghai Key Lab Chem Biol Shanghai 200237 Peoples R China;

E China Univ Sci &

Technol Sch Pharm Shanghai Key Lab Chem Biol Shanghai 200237 Peoples R China;

E China Univ Sci &

Technol Sch Pharm Shanghai Key Lab Chem Biol Shanghai 200237 Peoples R China;

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正文语种 eng
中图分类化学;
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专利

1. Perfluorobutyl iodide-assisted direct cyanomethylation of azoles and phenols with acetonitrile [J] . Zhang Juan, Wu Wei, Ji Xinfei, RSC Advances . 2015,第26期

机译：用乙腈的全氟丁基碘辅助直接氰基甲基化和苯酚
2. Iron(II)-catalyzed C-2 cyanomethylation of indoles and pyrroles via direct oxidative cross-dehydrogenative coupling with acetonitrile derivatives [J] . Qiao Kai, Zhang Dong, Zhang Kai, Organic Chemistry Frontiers . 2018,第7期

机译：铁（II）通过与乙腈衍生物的直接氧化交叉脱氢偶联催化吲哚和糊化糖催化的C-2氰基甲基化
3. Synthesis, structural configuration and DFT molecular orbital studies of [Mn-2[benzo[b]oxazole] acetonitrile] complexes encapsulated in ZSM-5: Direct synthesis of phenol by benzene hydroxylation [J] . Ali Ibraheem O., Hanafy Ahmed I., Salama Tarek M., Microporous and mesoporous materials: The offical journal of the International Zeolite Association . 2018,第期

机译：ZSM-5中包封的[Mn-2 [Benzo [B]氧化锆]乙腈络合物的合成，结构构型和DFT分子轨道研究：苯羟基化直接合成苯酚
4. Direct and catalytic reduction of 2,6-bis(chloromethyl)pyridine at carbon cathodes in acetonitrile [C] . Chang Ji, Mohammad S. Mubarak, Dennis G. Peters, International Symposium on Reactive Intermediates in Organic and Biological Electrochemistry . 2001

机译：在乙腈中的碳阴极下直接和催化还原2,6-双（氯甲基）吡啶
5. Studies on the reaction mechanism of phenol hydroxylase: Site-directed mutagenesis and 6-azido-FAD. [D] . Xu, Dong. 2003

机译：酚羟化酶反应机理的研究：定点诱变和6-叠氮基-FAD。
6. Palladium-catalyzed ligand-promoted site-selective cyanomethylation of unactivated C(sp3)–H bonds with acetonitrile [O] . Yongbing Liu, Ke Yang, Haibo Ge 2016

机译：钯催化未活化的C（sp3）–H键与乙腈的配位体促进位点选择性氰甲基化
7. Direct cyanomethylation of aliphatic and aromatic hydrocarbons with acetonitrile over a metal loaded titanium oxide photocatalyst [O] . Emiko Wada, Tomoaki Takeuchi, Yuki Fujimura, 2017

机译：用乙腈在金属负载氧化钛光催化剂上用脂族和芳烃的直接氰基甲基化

Perfluorobutyl iodide-assisted direct cyanomethylation of azoles and phenols with acetonitrile

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