Synthesis of fluorovinyl aryl ethers by a threecomponent reaction of gem-difluoroalkenes with arylboronic acids and oxygen

Wang Mingjin; Liang Fang; Xiong Yang; Cao Song

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Synthesis of fluorovinyl aryl ethers by a threecomponent reaction of gem-difluoroalkenes with arylboronic acids and oxygen

机译：用芳基硼酸和氧气的初始氟烯烃的三种组分反应合成氟乙烯基芳基醚

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摘要

A novel and efficient three-component reaction for the synthesis of fluorovinyl aryl ethers from gem-difluoroalkenes, arylboronic acids and oxygen under metal-free conditions is described.

机译：描述了一种新的和有效的三组分反应，用于在无金属条件下从Gem-Difluoro链烯，芳基硼酸和氧气中合成氟乙烯基芳基醚。

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《RSC Advances》 |2015年第16期|共4页
作者
Wang Mingjin; Liang Fang; Xiong Yang; Cao Song;
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ECUST Sch Pharm Shanghai Key Lab Chem Biol Shanghai 200237 Peoples R China;

ECUST Sch Pharm Shanghai Key Lab Chem Biol Shanghai 200237 Peoples R China;

ECUST Sch Pharm Shanghai Key Lab Chem Biol Shanghai 200237 Peoples R China;

ECUST Sch Pharm Shanghai Key Lab Chem Biol Shanghai 200237 Peoples R China;

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正文语种 eng
中图分类化学;
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1. Synthesis of fluorovinyl aryl ethers by a threecomponent reaction of gem-difluoroalkenes with arylboronic acids and oxygen [J] . Wang Mingjin, Liang Fang, Xiong Yang, RSC Advances . 2015,第16期

机译：用芳基硼酸和氧气的初始氟烯烃的三种组分反应合成氟乙烯基芳基醚
2. Synthesis and palladium(II) metal chemistry of thiazoline/imidazoline derived ligands: An efficient catalyst for cross-coupling reactions of arylboronic acids with acid chlorides and aryl halides [J] . Sudharsan Murugesan, Suresh D. Inorganica Chimica Acta . 2018,第期

机译：噻唑啉/咪唑啉衍生配体的合成和钯（II）金属化学：一种有效的芳基硼酸与酰氯和芳基卤化物的交联反应的有效催化剂
3. Aryl ketone synthesis via tandem orthoplatinated triarylphosphite-catalyzed addition reactions of arylboronic acids with aldehydes followed by oxidation [J] . Liao Y.-X., Hu Q.-S. The Journal of Organic Chemistry . 2010,第20期

机译：通过串联原位三亚磷酸三芳基酯催化的芳基硼酸与醛加成反应，然后氧化，合成芳基酮
4. Stereoselective Synthesis of alpha-Allenols by Rhodium-Catalyzed Arylative Ring-Opening Reaction of Alkynyl Oxiranes with Arylboronic Acids [C] . Masahiko Shimada, Tomoya Miura, Masahiro Murakami Symposium on Organometallic Chemistry . 2007

机译：芳基催化芳基苯甲酸芳基苯甲酸芳基苯甲酸芳基 - 苯甲酸芳基苯甲酸苯酚的立体选择性合成
5. I. TOTAL SYNTHESIS OF DL-CARNOSIC ACID DIMETHYL ETHER. II. ALTERNATE APPROACHES TO THE INTRODUCTION OF II-OXYGEN SUBSTITUENTS: TOTAL SYNTHESISOF DL-CARNOSOL DIMETHYL ETHER. [D] . SHEW, DELBERT CRAIG. 1969

机译：I.总的DL-己二酸二甲醚的合成。二。引入II-氧取代基的替代方法：完全合成DL-香辛醇二甲醚。
6. Aryl Ketone Synthesis via Tandem Orthoplatinated Triarylphosphite-Catalyzed Addition Reactions of Arylboronic Acids with Aldehydes Followed by Oxidation [O] . Yuan-Xi Liao, Qiao-Sheng Hu -1

机译：通过芳基硼酸与醛的串联Orthoplatinated三芳基亚磷酸酯催化加成反应的芳基酮的合成之后进行氧化
7. Palladium(II)-catalyzed Suzuki–Miyaura Reactions of Arylboronic Acid with Aryl Halide in the Presence of Aryl-Ferrocenyl-Phosphines [O] . A.T. Khabiyev, B.S. Selenova 2013

机译：钯（II） - 在芳基 - 二茂铁 - 膦酸氨基存在下，催化芳族酸芳族酸的辛酸氨基酸反应

Synthesis of fluorovinyl aryl ethers by a threecomponent reaction of gem-difluoroalkenes with arylboronic acids and oxygen

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