High HOMO levels and narrow energy band gaps of dithienogalloles

Matsumoto Takuya; Tanaka Kazuo; Chujo Yoshiki

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High HOMO levels and narrow energy band gaps of dithienogalloles

机译：高同性恋水平和Dithienogalloles的窄能带隙

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We synthesized dithieno[3,2-b:2',3'-d]galloles containing four-coordinated gallium atoms. It was found that dithienogalloles had high stability to air and moisture and showed narrower energy-band gaps than dithienosiloles which are commodity materials in organic opto and/or electronic devices. In addition, relatively-higher HOMO levels were observed from dithienogalloles than those of other dithienoheteroles from electrochemical measurements. We experimentally and theoretically demonstrated the electron-donating properties and resonance effects of galliumatoms of dithienogalloles.

机译：我们合成了Dithieno [3,2-B：2'，3'-D]含有四个协调镓原子的甘油。发现DithienogAlloles对空气和水分的稳定性高，并且显示比在有机光学和/或电子设备中的商品材料的二硫醚的较窄的节能间隙。此外，从二硫代铂观察到比电化学测量的其他二噻吩的二硫铝相对较高。我们在实验和理论上证明了二硫铝镓的锆镓的赋予性能和共振效应。

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《RSC Advances》 |2015年第68期|共5页
作者
Matsumoto Takuya; Tanaka Kazuo; Chujo Yoshiki;
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Kyoto Univ Grad Sch Engn Dept Polymer Chem Nishikyo Ku Kyoto 6158510 Japan;

Kyoto Univ Grad Sch Engn Dept Polymer Chem Nishikyo Ku Kyoto 6158510 Japan;

Kyoto Univ Grad Sch Engn Dept Polymer Chem Nishikyo Ku Kyoto 6158510 Japan;

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正文语种 eng
中图分类化学;
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1. High HOMO levels and narrow energy band gaps of dithienogalloles [J] . Matsumoto Takuya, Tanaka Kazuo, Chujo Yoshiki RSC Advances . 2015,第68期

机译：高同性恋水平和Dithienogalloles的窄能带隙
2. Narrow band gap D-A copolymer of indacenodithiophene and diketopyrrolopyrrole with deep HOMO level: Synthesis and application in field-effect transistors and polymer solar cells [J] . Wang X., Luo H., Sun Y., Journal of Polymer Science, Part A. Polymer Chemistry . 2012,第2期

机译：吲哚并二噻吩与二酮吡咯并吡咯的窄带隙D-A共聚物具有很强的HOMO能级：在场效应晶体管和聚合物太阳能电池中的合成及应用
3. Fine Tuning of HOMO Energy Levels for Low-Band-Gap Photovoltaic Copolymers Containing Cyclopentadithienopyrrole and Bithiazole Units [J] . Dha1970njaya Patra, Duryodhan Sahu, Harihara Padhy, Macromolecular Chemistry and Physics . 2011,第18期

机译：含环戊二噻吩并吡咯和联噻唑单元的低禁带光伏共聚物的HOMO能级的微调
4. HOMO-LUMO Energy Levels and the Bandgaps to Understand Porpc Photocatalytic Activity [C] . Jeffrey De Lile, Young-A Son, Seung Geol Lee Pacific Rim Meeting on Electrochemical and Solid-State Science . 2020

机译：Homo-Lumo能量水平和带隙，了解Porpc光催化活动
5. Electronic Structure and thermoelectric properties of narrow band gap semiconductors and pseudo-gap systems. [D] . Do, Dat Thanh. 2013

机译：窄带隙半导体和伪间隙系统的电子结构和热电性能。
6. Do HOMO–LUMO Energy Levels and Band Gaps ProvideSufficient Understanding of Dye-Sensitizer Activity Trends for WaterPurification? [O] . JeffreyRoshan De Lile, Sung Gu Kang, Young-A Son, 2020

机译：HOMO–LUMO能级和带隙是否提供对水的染料敏化剂活动趋势有足够的了解纯化？
7. High HOMO levels and narrow energy band gaps of dithienogalloles [O] . Matsumoto Takuya, Tanaka Kazuo, Chujo Yoshiki 2015

机译：高二茂铁水平和二噻吩甲酚的窄能带隙

High HOMO levels and narrow energy band gaps of dithienogalloles

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