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Graphene-modified BiMo0.03V0.97O4 thin-film photoanode for enhanced photoelectrochemical water splitting performance

机译:石墨烯改性的BIMO0.03V0.97O4薄膜光电码,用于增强光电化学水分解性能

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摘要

In this study, graphene is coated on the surface of an Mo-doped BiMo0.03V0.97O4 (BiMoVO) film by galvanostatic reduction deposition. The BiMoVO/graphene (BiMoVO/G) thin-film photoanode exhibits the optimal photoelectrochemical performance with the graphene deposition time of 600 s. The photoinduced current density is 3.5 mA cm(-2) at the bias potential of 1 V, which increases by approximately 2.3 times that of the BiMoVO thin-film photoanode. Moreover, the BiMoVO/G photoanode shows higher photoelectrochemical stability as well. The improvement of the photoelectrochemical properties is attributed to the graphene coating, which acts as the receptor of the photogenerated electrons from the BiMoVO film. Therefore, the photogenerated electrons can be rapidly transferred to the substrate through the graphene channel, enhancing the separation efficiency of the photogenerated electron-hole pairs and prolonging the lifetime of the photoinduced electrons.
机译:在该研究中,通过GALVANOTATIC沉积沉积在Mo掺杂的Bimo0.03v0.97O4(Bimovo)膜的表面上涂覆石墨烯。 Bimovo / Graphene(Bimovo / g)薄膜光电码显示出最佳光电化学性能,具有600秒的石墨烯沉积时间。 光突出电流密度在1V的偏置电位下为3.5mA cm(-2),这增加了Bimovo薄膜光电码的约2.3倍。 此外,Bimovo / G PhotoNode也显示出更高的光电化学稳定性。 光电化学性质的改善归因于石墨烯涂层,其用作来自Bimovo膜的光发生电子的受体。 因此,光生电子可以通过石墨烯通道快速转移到基板上,增强光发生的电子 - 空穴对的分离效率并延长光导电的寿命。

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  • 来源
    《RSC Advances》 |2015年第95期|共8页
  • 作者单位

    Qingdao Univ Sci &

    Technol Sch Environm &

    Safety Engn Qingdao 266042 Peoples R China;

    Qingdao Univ Sci &

    Technol Sch Environm &

    Safety Engn Qingdao 266042 Peoples R China;

    Chinese Acad Sci Inst Oceanol Key Lab Marine Environm Corros &

    Biofouling Qingdao 266071 Peoples R China;

    Chinese Acad Sci Inst Oceanol Key Lab Marine Environm Corros &

    Biofouling Qingdao 266071 Peoples R China;

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  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 化学;
  • 关键词

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