Copper ingrained poly(ethylene)glycols as cost effective and reusable media for selective 1-decene/n-decane separation

Varyani Manish; Ghosh Indrajit K.; Jain Suman L.

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Copper ingrained poly(ethylene)glycols as cost effective and reusable media for selective 1-decene/n-decane separation

机译：铜加入聚（乙烯）二醇作为成本效益和可重复使用的培养基，用于选择性1-癸烯/ N-癸烷分离

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Liquid range polyethylene glycols containing copper ions have been used as recyclable extractive media for the selective separation of 1-decene from a mixture of 1-decene and n-decane. The copper(II) ions in PEG were readily converted into copper(I) and then selectively coordinated with 1-decene molecules through pi-complexation. The resulting polyethylene glycol phase containing copper-olefin complex was treated with n-heptane at 70-80 degrees C to obtain pure 1-decene and the recovered poly(ethylene)glycol containing copper ions was successfully reused for several runs.

机译：含有铜离子的液体范围聚乙二醇已被用作可再循环的萃取介质，用于从1-癸烯和N-癸烷的混合物中选择性分离1-癸烯。 PEG中的铜（II）离子易于转化为铜（I），然后通过PI-络合选择性地用1-癸烯分子配位。将含有铜 - 烯烃复合物的聚乙二醇相在70-80℃下用正庚烷处理，得到纯1 - 癸烯，并成功再利用含有铜离子的回收的聚（乙烯）二醇。

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来源
《RSC Advances》 |2015年第94期|共5页
作者
Varyani Manish; Ghosh Indrajit K.; Jain Suman L.;
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Indian Inst Petr CSIR Div Chem Sci Dehra Dun 248005 Uttar Pradesh India;

Indian Inst Petr CSIR Div Chem Sci Dehra Dun 248005 Uttar Pradesh India;

Indian Inst Petr CSIR Div Chem Sci Dehra Dun 248005 Uttar Pradesh India;

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正文语种 eng
中图分类化学;
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1. Copper ingrained poly(ethylene)glycols as cost effective and reusable media for selective 1-decene/n-decane separation [J] . Varyani Manish, Ghosh Indrajit K., Jain Suman L. RSC Advances . 2015,第94期

机译：铜加入聚（乙烯）二醇作为成本效益和可重复使用的培养基，用于选择性1-癸烯/ N-癸烷分离
2. Effect of poly(ethylene glycol)molecular weight on CO2/N2 separation performance of poly(amide-12-b-ethylene oxide)/poly(ethylene glycol)blend membranes [J] . Shichao Feng, Jizhong Ren, Dan Zhao, 能源化学：英文版 . 2019,第001期

机译：聚乙二醇分子量对聚（酰胺-12-b-环氧乙烷）/聚乙二醇共混膜CO2 / N2分离性能的影响
3. Selective adsorption and reusability behavior for Pb2+ and Cd2+ on chitosan/poly(ethylene glycol)/poly(acrylic acid) adsorbent prepared by glow-discharge electrolysis plasma [J] . Yu Jie, Zheng Jidong, Lu Quanfang, Colloid and polymer science . 2016,第10期

机译：辉光放电电解等离子体制备的壳聚糖/聚乙二醇/聚丙烯酸对Pb2 +和Cd2 +的选择性吸附和重用性
4. Selective separation of poly(ethylene glycol) with different terminal groups using flexible MOFs [C] . Benjamin Le Ouay, Takashi Uemura 日本化学会春季年会講演予稿集 . 2018

机译：使用柔性MOF与不同末端基团的聚（乙二醇）的选择性分离
5. I. Diamino telechelic polybutadienes: Synthesis, characterization and melt coupling. II. Poly(epsilon-caprolactone-beta-poly(ethylene glycol) polymeric nanoparticles for drug delivery. III. Zirconia based cellulosic HPLC chiral stationary phase for enantioseparations. [D] . Ji, Shengxiang. 2006

机译：I.二氨基远螯聚丁二烯：合成，表征和熔融偶联。二。用于药物递送的聚（ε-己内酯-β-聚（乙二醇）聚合物纳米颗粒）III。用于对映体分离的基于氧化锆的纤维素HPLC手性固定相。
6. Docetaxel-Loaded Mixed Micelles and Polymersomes Composed of Poly (caprolactone)-Poly (ethylene glycol) (PEG-PCL) and Poly (lactic acid)-Poly (ethylene glycol) (PEG-PLA): Preparation and In-vitro Characterization [O] . Elham Khodaverdi, Zahra Tayarani-Najaran, Elham Minbashi, 2019

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7. Liquid-Liquid Phase Separation and Gelation in the Poly(vinyl alcohol)-Poly(ethylene glycol)–Water System. Dependence on Molecular Weight of Poly(ethylene glycol) [O] . Isamu Inamura 1986

机译：聚（乙烯醇） - 聚（乙二醇） - 水体系中的液 - 液相分离和凝胶化。依赖聚（乙二醇）的分子量

Copper ingrained poly(ethylene)glycols as cost effective and reusable media for selective 1-decene/n-decane separation

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