An X-ray powder diffraction study of the spin-crossover transition and structure of bis (2,6-dipyrazol-1-ylpyrazine)iron(II) perchlorate

Money VA.; Evans IR.; Elhaik J.; Halcrow MA.; Howard JAK.

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An X-ray powder diffraction study of the spin-crossover transition and structure of bis (2,6-dipyrazol-1-ylpyrazine)iron(II) perchlorate

机译：X射线粉末衍射研究高氯酸双（2,6-二吡唑-1-基吡嗪）铁（II）的自旋交叉转变和结构

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The crystal structure of the iron(II) spin-crossover compound [Fe(C10H8N6)(2)](ClO4)(2) in the high-spin state has been solved from powder X-ray diffraction data using the DASH program and refined using Rietveld refinement. The thermal spin transition has been monitored by following the change in unit-cell parameters with temperature. The title compound has been found to undergo a crystallographic phase change, involving a doubling of the crystallographic a axis, on undergoing the spin transition. [References: 17]

机译：使用DASH程序从粉末X射线衍射数据解析了高自旋态的铁（II）自旋交联化合物[Fe（C10H8N6）（2）]（ClO4）（2）的晶体结构，并对其进行了精制使用Rietveld改进。通过跟踪晶胞参数随温度的变化来监测热自旋转变。已经发现标题化合物在经历自旋转变时经历晶体学相变，包括晶体学a轴加倍。 [参考：17]

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《Acta Crystallographica, Section B. Structural Science》 |2004年第1期|共5页
作者
Money VA.; Evans IR.; Elhaik J.; Halcrow MA.; Howard JAK.;
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正文语种 eng
中图分类晶体学;
关键词
Iron(ii) complexes; State transition; Unit-cell; L=2; 6-di(pyrazol-1-yl)pyridine; Refinement;

机译：铁（ii）配合物;状态转变;晶胞;L = 2;6-二（吡唑-1-基）吡啶;精制;

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1. An X-ray powder diffraction study of the spin-crossover transition and structure of bis (2,6-dipyrazol-1-ylpyrazine)iron(II) perchlorate [J] . Money VA., Evans IR., Elhaik J., Acta Crystallographica, Section B. Structural Science . 2004,第1期

机译：X射线粉末衍射研究高氯酸双（2,6-二吡唑-1-基吡嗪）铁（II）的自旋交叉转变和结构
2. STRUCTURAL AND QUANTUM CHEMICAL STUDY OF BI-5(3+) AND ISOELECTRONIC MAIN-GROUP METAL CLUSTERS - THE CRYSTAL STRUCTURE OF PENTABISMUTH(3+) TETRACHLOROGALLATE(III) REFINED FROM X-RAY POWDER DIFFRACTION DATA AND SYNTHETIC ATTEMPTS ON ITS ANTIMONY ANALOG [J] . Ulvenlund S., Bengtssonkloo L., Stahl K. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1996,第1期

机译：BI-5（3+）和等电子主团簇的结构和量子化学研究-由X射线粉末衍射数据和模拟合成的尝试确定的五溴（5+）四氟甲酸酯（III）的晶体结构
3. The crystal structures of the binary mixed valence compound (Bi3BiO7)-Bi-(III)-O-(V) and isotypic Bi3SbO7 as determined by high resolution X-ray and neutron powder diffraction [J] . Dinnebier RE., Ibberson RM., Ehrenberg H., International Journal of Quantum Chemistry . 2002,第1期

机译：通过高分辨率X射线和中子粉末衍射测定的二元混合价化合物（Bi3BiO7）-Bi-（III）-O-（V）和同型Bi3SbO7的晶体结构
4. Substituent Effect in Spin-Crossover Behavior of Iron(II)-Ar-pybox Complexes (Ar-pybox= 4-Aryl-2,6-bis(oxazolin-2-yl)pyridine) [C] . Akifumi Kimura, Takayuki Ishida Irago Conference . 2018

机译：铁（II）-AR-ubox络合物的旋转交叉行为中的取代基效应（Ar-pybox = 4-芳基-2,6-双（恶唑啉-2-基）吡啶）
5. A study of the growth and structure of chromium and iron oxide films on palladium(001) using X-ray photoelectron diffraction and low energy electron diffraction [D] . Dhekial Phukan, Tina 2010

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6. Crystal structure of bis(1-ammonio-1-phosphonoethyl)phosphonatotetraaquacadmium dihydrate: a powder X-ray diffraction study [O] . Mwaffak Rukiah, Thaer Assaad 2015

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7. Spin State Behavior of A Spin-Crossover Iron(II) Complex with N,N′-Disubstituted 2,6-bis(pyrazol-3-yl)pyridine: A Combined Study by X-ray Diffraction and NMR Spectroscopy [O] . Elizaveta Melnikova, Dmitry Aleshin, Igor Nikovskiy, 2020

机译：与N，N'-二取代的2,6-双（吡唑-3-基）吡啶的旋转交叉铁（II）复合物的旋转状态行为：X射线衍射和NMR光谱的组合研究
8. Moessbauer Study of Some Iron (III) Complexes with Urea-Type Ligands and Crystal Structure of Hexakisdimethylurea Iron (III) Perchlorate [R] . Calogero, S., Galeazzi, G., Russo, U., 1980

机译：moessbauer研究一些具有尿素型配体的铁（III）配合物和Hexakisdimethylurea铁（III）高氯酸盐的晶体结构

An X-ray powder diffraction study of the spin-crossover transition and structure of bis (2,6-dipyrazol-1-ylpyrazine)iron(II) perchlorate

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