Structures from MnX_ 2 and proline: Isomorphous racemic compounds and a series of chiral non-isomorphous chain polymers

Lamberts K.; Englert U.

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Structures from MnX_ 2 and proline: Isomorphous racemic compounds and a series of chiral non-isomorphous chain polymers

机译：MnX_2和脯氨酸的结构：同构外消旋化合物和一系列手性非同构链聚合物

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Reactions of manganese(II) chloride, bromide and iodide with proline as an enantiopure and racemic ligand result in six crystalline solids for which diffraction experiments have been performed at 100 K. For two of these compounds, crystal structures at ambient temperature had been reported previously. The most surprising outcome of our systematic comparison lies in the role of chirality: with enantiopure proline three different coordination polymers have been obtained, whereas racemic proline yields isomorphous mononuclear complexes under the same reaction conditions.

机译：氯化锰（II），溴化物和碘化物与脯氨酸的对映体和外消旋配体的反应产生了六种结晶固体，已在100 K下进行了衍射实验。对于其中的两种化合物，先前已报道了室温下的晶体结构。我们系统比较的最令人惊讶的结果是手性的作用：通过对映纯脯氨酸获得了三种不同的配位聚合物，而外消旋脯氨酸在相同的反应条件下产生了同构的单核络合物。

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《Acta Crystallographica, Section B. Structural Science》 |2012年第6期|共9页
作者
Lamberts K.; Englert U.;
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正文语种 eng
中图分类晶体学;
关键词
chirality; coordination polymers; isomorphous mononuclear complexes;

机译：手性;配位聚合物;同构单核配合物;

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1. Structures from MnX_ 2 and proline: Isomorphous racemic compounds and a series of chiral non-isomorphous chain polymers [J] . Lamberts K., Englert U. Acta Crystallographica, Section B. Structural Science . 2012,第6期

机译：MnX_2和脯氨酸的结构：同构外消旋化合物和一系列手性非同构链聚合物
2. The non-isomorphous crystal structures of NHC—Au—Cl and NHC—Au—Br (NHC is 1,3-dibenzyl-4,5-diphenylimidazol-2-ylidene) [J] . Matthias Tacke, Oyinlola Dada, Cillian OBeirne, Acta crystallographica. Section C, Structural chemistry. . 2016,第11期

机译：NHC-Au-Cl和NHC-Au-Br（NHC为1,3-二苄基-4,5-二苯基咪唑-2- ylidene）的非同种同种异构晶体结构
3. The non-isomorphous crystal structures of NHC-Au-Cl and NHC-Au-Br (NHC is 1,3-dibenzyl-4,5-diphenylimidazol-2-ylidene) [J] . Tacke Matthias, Dada Oyinlola, OBeirne Cillian, Acta crystallographica. Section F, Structural biology communications . 2016,第11期

机译：NHC-Au-Cl和NHC-Au-Br（NHC为1,3-二苄基-4,5-二苯基咪唑-2- ylidene）的非同种同种异构晶体结构
4. Optical resolution of racemic compounds by chiral HPLC on immobilized amylose derivatives with regioselective substituents [C] . Shen Jun, Liu Shuangyan, Li Pengfei, 2011 IEEE/ICME International Conference on Complex Medical Engineering . 2011

机译：通过手性HPLC在具有区域选择性取代基的固定直链淀粉衍生物上光学拆分外消旋化合物
5. I. Novel side chain liquid crystalline polymers as nonlinear optical materials. II. Main chain liquid crystalline polymers and polymer model compounds. [D] . Hung, Sywe-Liang Robert. 1987

机译：I.新型侧链液晶聚合物作为非线性光学材料。二。主链液晶聚合物和聚合物模型化合物。
6. Polymerization Special Feature: Kinetic resolution of racemic α-olefins with ansa-zirconocene polymerization catalysts: Enantiomorphic site vs. chain end control [O] . Jeffery A. Byers, John E. Bercaw 2006

机译：聚合特性：用ansa-zirconocene聚合催化剂动力学拆分外消旋α-烯烃：对映体位点与链端控制
7. Structures from MnX2 and proline: isomorphous racemic compounds and a series of chiral non-isomorphous chain polymers [O] . Lamberts Kevin, Englert Ullrich 2012

机译：MnX2和脯氨酸的结构：同构外消旋化合物和一系列手性非同构链聚合物
8. Chain Growth Cross Coupling Polymerizations Towards Chiral and Ladder Main Chain Polymers. [R] . Xia, Y. 2014

机译：链增长交叉聚合聚合手性和梯形主链聚合物。

Structures from MnX_ 2 and proline: Isomorphous racemic compounds and a series of chiral non-isomorphous chain polymers

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