An order-disorder phase transition in the structure of C _60 · 4benzene

Olmstead M.M.; Balch A.L.; Lee H.M.

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An order-disorder phase transition in the structure of C _60 · 4benzene

机译：C _60·4苯结构的有序无序相变

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摘要

A reversible, broad, order-disorder phase transition in the structure of C _60 · 4benzene has been observed to take place with an inflection point at 134 K. In the low-temperature structure fullerene disorder is removed, although the average atomic displacement parameters differ for the two C _60 molecules in the asymmetric unit. Some benzene disorder persists, even at 13 K.

机译：已观察到C _60·4苯结构中发生可逆的，宽泛的，有序的相变，拐点在134 K处发生。在低温结构中，尽管平均原子置换参数不同，但富勒烯无序被去除。对于不对称单元中的两个C _60分子。甚至在13 K时，仍然存在一些苯紊乱。

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《Acta Crystallographica, Section B. Structural Science》 |2012年第1期|共5页
作者
Olmstead M.M.; Balch A.L.; Lee H.M.;
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正文语种 eng
中图分类晶体学;
关键词
60fullerene; order-disorder; phase transition;

机译：[60]富勒烯;无序;相变;

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1. An order-disorder phase transition in the structure of C _60 · 4benzene [J] . Olmstead M.M., Balch A.L., Lee H.M. Acta Crystallographica, Section B. Structural Science . 2012,第1期

机译：C _60·4苯结构的有序无序相变
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6. Orientational order-disorder γ ↔ β ↔ α′ ↔ α phase transitions in Sr2B2O5 pyroborate and crystal structures of β and α phases [O] . Sergey Volkov, Michal Dušek, Rimma Bubnova, -1

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An order-disorder phase transition in the structure of C _60 · 4benzene

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