Distortion of crystal structures of some Co-III ammine complexes .1. Distortion of crystal structure of [Co(NH3)(5)NO2]Cl(NO3) on cooling

Boldyreva E; Kivikoski J; Howard JAK; UNIV DURHAM DEPT CHEM SCI LABS DURHAM DH1 3LE ENGLAND.

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Distortion of crystal structures of some Co-III ammine complexes .1. Distortion of crystal structure of [Co(NH3)(5)NO2]Cl(NO3) on cooling

机译：某些Co-III氨基配合物的晶体结构变形1。冷却时[Co（NH3）（5）NO2] Cl（NO3）的晶体结构变形

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The anisotropy of the structural distortion of [Co-(NH3)(5)NO2]Cl(NO3), pentaamminenitrocobalt(III) chloride nitrate, on cooling from 290 to 150 K was studied by variable-temperature single-crystal X-ray diffraction. The changes in lattice parameters were used to calculate the strain tensors and to scan linear distortion in various crystallographic directions. The changes of different intra- and intermolecular distances in the structure were followed. Lattice strain induced by low temperature was compared with lattice strain in the same structure under high hydrostatic pressure and with lattice strain induced by homogeneous nitro-nitrito linkage isomerization.

机译：通过变温单晶X射线衍射研究了[Co-（NH3）（5）NO2] Cl（NO3），五胺硝基氯化钴（III）硝酸盐在冷却至290至150 K时的结构各向异性。。晶格参数的变化用于计算应变张量并扫描各个晶体学方向上的线性变形。跟踪结构中不同的分子内和分子间距离的变化。将低温诱导的晶格应变与相同结构在高静水压力下的晶格应变以及均相的硝基-腈键异构化诱导的晶格应变进行了比较。

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《Acta Crystallographica, Section B. Structural Science》 |1997年第3期|共11页
作者
Boldyreva E; Kivikoski J; Howard JAK; UNIV DURHAM DEPT CHEM SCI LABS DURHAM DH1 3LE ENGLAND.;
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正文语种 eng
中图分类晶体学;
关键词
SOLID-STATE CHEMISTRY; CO(III)-AMMINE COMPLEXES; LINKAGE ISOMERIZATION; NEUTRON-DIFFRACTION; THERMAL-EXPANSION; HIGH-PRESSURE; DEFORMATION; REACTIVITY; DEPENDENCE; TENSORS;

机译：固态化学;CO（III）-氨络合物;键合异构化;中子衍射;热膨胀;高压;变形;反应性;依赖性;张量;

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1. Distortion of crystal structures of some Co-III ammine complexes .1. Distortion of crystal structure of [Co(NH3)(5)NO2]Cl(NO3) on cooling [J] . Boldyreva E, Kivikoski J, Howard JAK, Acta Crystallographica, Section B. Structural Science . 1997,第3期

机译：某些Co-III氨基配合物的晶体结构变形1。冷却时[Co（NH3）（5）NO2] Cl（NO3）的晶体结构变形
2. Distortion of crystal structures of some Co-III ammine complexes .2. Distortion of crystal structures of [Co(NH3)(5)NO2]X-2 (X=Cl, Br) on cooling [J] . Boldyreva E, Kivikoski J, Howard JAK, Acta Crystallographica, Section B. Structural Science . 1997,第3期

机译：某些Co-III胺配合物的晶体结构畸变.2。冷却时[Co（NH3）（5）NO2] X-2（X = Cl，Br）的晶体结构变形
3. Distortion of crystal structures of some Co-III ammine complexes. III. Distortion of crystal structure of [Co(NH3)(5)NO2]Cl-2 at hydrostatic pressures up to 3.5 GPa [J] . Boldyreva EV., Ahsbahs H., Naumov DY. Acta Crystallographica, Section B. Structural Science . 1998,第6期

机译：某些Co-III氨基配合物的晶体结构变形。三， [Co（NH3）（5）NO2] Cl-2在高达3.5 GPa的静水压力下的晶体结构变形
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机译：钯配合物的晶体结构为6-氧气3,9-dithiaWclo 9,4,0 - 戊烷-1（11），12,14-三烯（L），顺式-X2LPD（II）（x = NO3， SCN）。

Distortion of crystal structures of some Co-III ammine complexes .1. Distortion of crystal structure of [Co(NH3)(5)NO2]Cl(NO3) on cooling

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