Synthesis and structural characterization of donorstabilized disubstituted diphenyldithiophosphates of nickel(II)

Sandeep Kumar; Ruchi Khajuria; Amanpreet Kaur Jassal; Geeta Hundal; Maninder S. Hundal; Sushil K. Pandey

首页> 外文期刊>Acta Crystallographica, Section B. Structural Science >Synthesis and structural characterization of donorstabilized disubstituted diphenyldithiophosphates of nickel(II)

【24h】

Synthesis and structural characterization of donorstabilized disubstituted diphenyldithiophosphates of nickel(II)

机译：供体稳定的镍取代的二取代的二苯基二硫代磷酸酯的合成及结构表征

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Donor-stabilized addition complexes of nickel(II) with disubstituted diphenyldithiophosphates, [{(ArO)_2PS_2}_2NiL_2] {Ar = 2,4-(CH_3)_2C_6H_3 [(1), (5)], 2,5-(CH_3)_2C_6H_3 [(2), (6)], 3,4-(CH_3)_2C_6H_3 [(3), (7)] and 3,5-(CH_3)_2C_6H_3 [(4), (8)]; L = C_5H_5N [(1)-(4)] and C_7H_9N [(5)-(8)]}, were successfully isolated and characterized by elemental analysis, magnetic moment, IR spectroscopy and single-crystal X-ray analysis. Compound (4) crystallizes in the monoclinic space group P2_1 whereas compounds (7) and (8) crystallize in the triclinic space group P1. The single-crystal X-ray diffraction analysis of (4), (7) and (8) reveals a six-coordinated octahedral geometry for the NiS_4N_2 chromophore. Two diphenyldithiophosphate ions act as bidentate ligands with their S atoms coordinated to the Ni centre. Each of them forms a four-membered chelate ring in the equatorial plane. The N atoms from two donor ligands are axially coordinated to the Ni atom.

机译：镍（II）与双取代的二苯基二硫代磷酸酯[[（（ArO）_2PS_2} _2NiL_2] {Ar = 2,4-（CH_3）_2C_6H_3 [（1），（5）]，2,5-（CH_3）的供体稳定的加成络合物）_2C_6H_3 [（2），（6）]，3,4-（CH_3）_2C_6H_3 [（3），（7）]和3,5-（CH_3）_2C_6H_3 [（4），（8）]; L = C_5H_5N [（1）-（4）]和C_7H_9N [（5）-（8）]}已成功分离，并通过元素分析，磁矩，IR光谱和单晶X射线分析进行了表征。化合物（4）在单斜空间群P2_1 / n中结晶，而化合物（7）和（8）在三斜晶空间群P1中结晶。（4），（7）和（8）的单晶X射线衍射分析揭示了NiS_4N_2发色团的六配位八面体几何形状。两个二苯基二硫代磷酸根离子充当双齿配体，其S原子与Ni中心配位。它们每个都在赤道平面上形成一个四元螯合环。来自两个供体配体的N原子与Ni原子轴向配位。

著录项

来源
《Acta Crystallographica, Section B. Structural Science》 |2014年第4期|共7页
作者
Sandeep Kumar; Ruchi Khajuria; Amanpreet Kaur Jassal; Geeta Hundal; Maninder S. Hundal; Sushil K. Pandey;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类晶体学;
关键词
Synthesis; structural; characterization;

机译：合成;结构;表征;

相似文献

外文文献
中文文献
专利

1. Synthesis and structural characterization of donorstabilized disubstituted diphenyldithiophosphates of nickel(II) [J] . Sandeep Kumar, Ruchi Khajuria, Amanpreet Kaur Jassal, Acta Crystallographica, Section B. Structural Science . 2014,第4期

机译：供体稳定的镍取代的二取代的二苯基二硫代磷酸酯的合成及结构表征
2. The first nickel(II) complexes of disubstituted diphenyldithiophosphates: Synthesis, spectroscopic, electrochemical, antifungal and single crystal X-ray analysis [J] . Sandeep Kumar, Ruchi Khajuria, Vivek K. Gupta, Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2014,第Null期

机译：二取代二苯基二硫代磷酸酯的首批镍（II）配合物：合成，光谱，电化学，抗真菌和单晶X射线分析
3. FIRST DONOR-STABILIZED COMPLEXES OF MANGANESE(II) WITH DISUBSTITUTED DIPHENYLDITHIOPHOSPHATES: SYNTHESIS, CHARACTERIZATION, BIOLOGICAL, AND X-RAY ANALYSIS [J] . Sajgotra Mehak, Khajuria Ruchi, Kumar Sandeep, Phosphorus, Sulfur, and Silicon and the Related Elements . 2015,第10a12期

机译：锰（II）与二苯二甲硫代磷酸酯取代的第一个供体稳定化的络合物：合成，表征，生物学和X射线分析
4. Synthesis and Structural Characterization of New Dithiocarbamate Complexes From Sb(III) and Bi(III) [C] . Nur Amirah Jamaluddin, Ibrahim Baba UKM FST Postgraduate Colloquium . 2013

机译：来自SB（III）和BI（III）的新二硫代氨基磺酸酯复合物的合成与结构表征
5. Part I. Synthesis of cytochrome P450-CAM substrate analogues towards developing cytochrome P450-CAM as an enzyme-based model system for mechanistic studies of important types of P450 reactions. Part II. Diels-Alder approach towards the synthesis of 2,3-disubstituted anthracene derivatives for luminescence spectroscopy characterization: Synthesis towards fluorescent sensors. [D] . Kemnitzer, William Edward. 1998

机译：第一部分。合成细胞色素P450-CAM底物类似物，以开发细胞色素P450-CAM作为一种基于酶的模型系统，用于重要类型P450反应的机理研究。第二部分Diels-Alder合成2,3-二取代蒽衍生物以进行发光光谱表征的方法：合成荧光传感器。
6. Synthesis and Crystal Structure of Hexakis(imidazole) nickel (II) OO′-diphenyldithiophosphate Ni(Im)6(Ph2O2PS2)2 [O] . Shusheng Zhang, Shiying Wang, Yonghong Wen, 2003

机译：六（咪唑）镍（II）OO-二苯基二硫代磷酸Ni（Im）6（Ph2O2PS2）2的合成及晶体结构
7. Nickel(II)Nickel(II) Azadithiolates: Synthesis Structural Characterization, and Electrocatalytic H2 Production [O] . -1

机译：镍（II）镍（II）四硫酸盐：合成结构表征和电催化H2生产
8. Metal Atom Synthesis of Metallaboron Clusters. 8. Synthesis of New Cobalt, Iron, and Nickel Clusters Derived from 2,6-C2B7H11. Structural Characterization of 2-ETA 6-C6(CH3)3H3 Fe-1,6-C2B7H9, 6-ETA 6-C6(CH3)3H3 Fe-9,10-C2B7H11, an [R] . Sneddon, L. G., Briguglio, J. J. 1986

机译：metallaboron团簇的金属原子合成。 8.衍生自2,6-C2B7H11的新的钴，铁和镍簇的合成。 2-ETa 6-C6（CH3）3H3Fe-1,6-C2B7H9,6-ETa6-C6（CH3）3H3Fe-9,10-C2B7H11的结构表征

Synthesis and structural characterization of donorstabilized disubstituted diphenyldithiophosphates of nickel(II)

摘要

著录项

相似文献

相关主题

期刊订阅