The two-dimensional coordination polymer poly[di-aqua-(μ2-1H- imid-azo[4,5-f][1,10]phenanthroline)-μ4-sulfato-μ3- sulfato-dicadmium(II)]

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The two-dimensional coordination polymer poly[di-aqua-(μ2-1H- imid-azo[4,5-f][1,10]phenanthroline)-μ4-sulfato-μ3- sulfato-dicadmium(II)]

机译：二维配位聚合物聚[di-aqua-（μ2-1H-咪唑-偶氮[4,5-f] [1,10]菲咯啉）-μ4-硫酸根-μ3-硫酸根-二镉（II）]

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In the title coordination polymer, [Cd2(SO4)2(C13H8N4)(H2O)2] n , there are two crystallographically independent CdII centres with different coordination geometries. The first CdII centre is hexacoordinated by four O atoms of four sulfate ligands, one water O atom and one N atom of a 1H-imid-azo[4,5-f][1,10]phenanthroline (IP) ligand, giving a distorted octa-hedral coordination environment. The second CdII centre is heptacoordinated by four O atoms of three sulfate ligands, one water O atom and two N atoms of one chelating IP ligand, resulting in a distorted monocapped anti-trigonal prismatic geometry. The symmetry-independent CdII ions are bridged in an alternating fashion by sulfate ligands, forming one-dimensional ladder-like chains which are connected through the IP ligands to form two-dimensional layers. These two-dimensional layers are linked by inter-layer hydrogen bonds, leading to the formation of a three-dimensional supra-molecular network.

机译：在标题配位聚合物[Cd2（SO4）2（C13H8N4）（H2O）2] n中，有两个晶体学独立的CdII中心，具有不同的配位几何形状。第一个CdII中心被四个硫酸盐配体的四个O原子，一个1H-咪唑-偶氮[4,5-f] [1,10]菲咯啉（IP）配体的一个水O原子和一个N原子六配位，得到一个扭曲的八面体协调环境。第二个CdII中心由三个硫酸盐配体的四个O原子，一个水合O原子和一个螯合IP配体的两个N原子七元配位，导致扭曲的单封端反三角棱柱形几何形状。不对称的CdII离子通过硫酸盐配体以交替的方式桥接，形成一维梯状链，这些链通过IP配体连接形成二维层。这些二维层通过层间氢键连接，导致形成三维超分子网络。

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《Acta crystallographica. Section C, Structural chemistry.》 |2014年第8期|共3页
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正文语种 eng
中图分类晶体学;
关键词
1H-imidazo4; 5-f1; 10phenanthroline; cadmium(II) complex; crystal engineering; crystal structure; hydrogen bonding; sulfate ions; two-dimensional coordination polymer;

机译：1H-咪唑并[4;5-f] [1;10]菲咯啉;镉（II）配合物;晶体工程;晶体结构;氢键;硫酸根离子;二维配位聚合物;

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1. The two-dimensional coordination polymer poly[di-aqua-(μ2-1H- imid-azo[4,5-f][1,10]phenanthroline)-μ4-sulfato-μ3- sulfato-dicadmium(II)] [J] . Acta crystallographica. Section C, Structural chemistry. . 2014,第8期

机译：二维配位聚合物聚[di-aqua-（μ2-1H-咪唑-偶氮[4,5-f] [1,10]菲咯啉）-μ4-硫酸根-μ3-硫酸根-二镉（II）]
2. Synthesis, structures, fluorescence properties, and natural bond orbital (NBO) analysis of two metal [Eu~(III), Co~(II)] coordination polymers containing 1, 3-benzenedicarboxylate and 2-(4-methoxyphenyl)-1H- imidazo[4,5-f][1,10]phenanthroline ligands [J] . Wang L., Jun Z., Ni L., Zeitschrift fur Anorganische und Allgemeine Chemie . 2012,第1期

机译：含1、3-苯二甲酸和2-（4-甲氧基苯基）-1H-的两种金属[Eu〜（III），Co〜（II）]配位聚合物的合成，结构，荧光性质和天然键轨道（NBO）分析咪唑并[4,5-f] [1,10]菲咯啉配体
3. Hydrothermal Synthesis, Crystal Structure, and Photoluminescence of Pb(II) and Mn(II) Coordination Polymers Based on Imidazo[4,5-f][1,10]phenanthroline1 [J] . K. Cheng, X. L. Zhang Russian Journal of Coordination Chemistry . 2013,第6期

机译：基于咪唑并[4,5-f] [1,10]菲咯啉1的Pb（II）和Mn（II）配位聚合物的水热合成，晶体结构和光致发光
4. Effect of pH on the formation of poly Fe (III)-S-Amino 1,10 phenanthroline [C] . M. L. Lozano, L. Galicia MES 24: Electrochemical applications to biology, nanotechnology, and environmental engineering and materials . 2009

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5. Synthesis and crystal structure of a two-dimensional CoII coordination polymer: poly(μ3-3-carboxybenzoato)μ2-5-(pyridin-4-yl)-1H2′H-33′-bi124-triazolecobalt(II) [O] . Chao-Jun Du, Xiao-Na Zhao, Bao-Yong Chen 2017

机译：二维CoII配位聚合物：聚（μ3-3-羧基苯并）μ2-5-（吡啶-4-基）-1H2′H-33′-bi 1 24-三唑钴（II）
6. catena-Poly[[(1,10-phenanthroline-κ2 N,N′)lead(II)]-μ-azido-κ2 N 1:N 3-μ-nitrito-κ3 O,O′:O′-[(1,10-phenanthroline-κ2 N,N′)lead(II)]-di-μ-azido-κ4 N 1:N 1] [O] . Mohammadnezhad, Gholamhossein, Ghanbarpour, Ali Reza, Amini, Mostafa M., 2010

机译：阳离子多聚[[（（1,10-菲咯啉-κ2 N，N'）铅（II）]-μ-叠氮基-κ2 ñ 1：N 3-μ-硝化κ3 O，O'：O.-[（（1,10-菲咯啉-κ2 N，N'）铅（II）]-di-μ-叠氮基-κ4 ñ 1：N 1]
7. Electrochemistry and Spectroelectrochemistry in CH3CN and Aluminum Chloride/N-(1-Butyl)pyridinium Chloride Molten Salts of Films Prepared by Electrochemical Polymerization of Tris(5-amino-1,10-phenanthroline)iron(II) [R] . Osteryoung, R. A., Pickup, P. G. 1985

机译：三（5-氨基-1,10-菲咯啉）铁（II）电化学聚合制备的CH3CN和氯化铝/ N-（1-丁基）吡啶氯化物熔盐的电化学和光谱电化学

The two-dimensional coordination polymer poly[di-aqua-(μ2-1H- imid-azo[4,5-f][1,10]phenanthroline)-μ4-sulfato-μ3- sulfato-dicadmium(II)]

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