首页> 外文期刊>Acta crystallographica. Section C, Structural chemistry. >A two-dimensional ZnII coordination polymer constructed from benzene-1,2,3-tricarboxylic acid and N,N'-bis[(pyridin-4-yl)methylidene]hydrazine
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A two-dimensional ZnII coordination polymer constructed from benzene-1,2,3-tricarboxylic acid and N,N'-bis[(pyridin-4-yl)methylidene]hydrazine

机译:由苯1,2,3-三羧酸和N,N'-双[(吡啶-4-基)亚甲基]肼构成的二维ZnII配位聚合物

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摘要

The construction of novel metal-organic coordination polymers (CPs) continues to attract great interest due to their potential applications in many fields, such as catalysis, luminescence and magnetochemistry, as well as their intriguing variety of architectures and topologies (Kitagawa et al., 2004; Rowsell & Yaghi, 2005; Furukawa et al., 2013; Cui et al., 2012; Sun et al., 2010). The selection of the organic ligands plays a crucial role as even small changes in the conformation or symmetry of the ligands can result in a remarkable diversity of architectures and functions (Adarsh et al., 2009; Liu & Telfer, 2015). Aromatic polycarboxylates are used frequently in this strategy because they have rigid organic skeletons, excellent coordination capabilities and flexible coordination patterns (Breeze et al., 2013; Luo et al., 2013; Zhao et al., 2014)..
机译:由于新型金属有机配位聚合物(CPs)在催化,发光和磁化学等许多领域中的潜在应用以及引人入胜的各种结构和拓扑结构,继续引起人们的极大兴趣(Kitagawa等, 2004; Rowsell&Yaghi,2005; Furukawa等人,2013; Cui等人,2012; Sun等人,2010)。有机配体的选择起着至关重要的作用,因为即使配体的构象或对称性发生微小变化,也会导致结构和功能的显着多样性(Adarsh等,2009; Liu&Telfer,2015)。芳香族多羧酸盐由于具有刚性的有机骨架,出色的配位能力和灵活的配位方式而在该策略中得到了广泛使用(Breeze等人,2013; Luo等人,2013; Zhao等人,2014)。

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