Poly[[chlorido(1,10-phenanthroline-κ2N,N')copper(II)]-μ3-1,1,3,3-tetracyano-2-ethoxypropenido-κ3N:N':N'']: coordination polymer sheets linked into bilayers by hydrogen bonds.

SetifiZ.; SetifiF.; ElAmmariL.; El-GhozziM.; Sopková-deOliveiraSantosJ.; MerazigH.; GlidewellC.

首页> 外文期刊>Acta crystallographica. Section C, Structural chemistry. >Poly[[chlorido(1,10-phenanthroline-κ2N,N')copper(II)]-μ3-1,1,3,3-tetracyano-2-ethoxypropenido-κ3N:N':N'']: coordination polymer sheets linked into bilayers by hydrogen bonds.

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Poly[[chlorido(1,10-phenanthroline-κ2N,N')copper(II)]-μ3-1,1,3,3-tetracyano-2-ethoxypropenido-κ3N:N':N'']: coordination polymer sheets linked into bilayers by hydrogen bonds.

机译：聚[[氯（1,10-菲咯啉-κ2N，N'）铜（II）]-μ3-1,1,3,3-四氰基-2-乙氧基丙烯-κ3N：N'：N'']：配位聚合物片通过氢键连接成双层。

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In the title compound, [Cu(C9H5N4O)Cl(C12H8N2)]n or [Cu(tcnoet)Cl(phen)]n, where phen is 1,10-phenanthroline and tcnoet is 1,1,3,3-tetracyano-2-ethoxypropenide, the axially elongated (4 + 2) coordination polyhedron around the Cu(II) centre contains N atoms from three different tcnoet ligands. The resulting coordination polymer takes the form of sheets which are linked in pairs by a single C-H...N hydrogen bond to form bilayers. The bond lengths provide evidence for significant bond fixation in the phen ligand and extensive electronic delocalization in the tcnoet ligand, where the two -C(CN)2 units are rotated, in conrotatory fashion, out of the plane of the central C3O fragment.

机译：在标题化合物中，[Cu（C9H5N4O）Cl（C12H8N2）] n或[Cu（tcnoet）Cl（phen）] n，其中phen是1,10-菲咯啉，tcnoet是1,1,3,3-四氰基- 2-乙氧基丙烯，围绕Cu（II）中心的轴向延长（4 + 2）配位多面体，包含来自三个不同tcnoet配体的N原子。所得的配位聚合物呈片状，其通过单个C-H ... N氢键成对连接以形成双层。键的长度为phen配体中明显的键固定和tcnoet配体中广泛的电子离域提供了证据，其中两个-C（CN）2单元以旋转方式从中心C3O片段的平面旋转出来。

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《Acta crystallographica. Section C, Structural chemistry.》 |2014年第1期|共4页
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SetifiZ.; SetifiF.; ElAmmariL.; El-GhozziM.; Sopková-deOliveiraSantosJ.; MerazigH.; GlidewellC.;
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1. Poly[[chlorido(1,10-phenanthroline-κ2N,N')copper(II)]-μ3-1,1,3,3-tetracyano-2-ethoxypropenido-κ3N:N':N'']: coordination polymer sheets linked into bilayers by hydrogen bonds. [J] . SetifiZ., SetifiF., ElAmmariL., Acta crystallographica. Section C, Structural chemistry. . 2014,第1期

机译：聚[[氯（1,10-菲咯啉-κ2N，N'）铜（II）]-μ3-1,1,3,3-四氰基-2-乙氧基丙烯-κ3N：N'：N'']：配位聚合物片通过氢键连接成双层。
2. Coordination chemistry of the ligand 7-aza-1-hydroxy-benzotriazole. Crystal structures and antimicrobial activity of the catena-poly-[μ-chlorido(μ-7- aza-1-oxy-κ~2N:O-benzotriazolyl-κN)]cobalt(II)methanol coordination polymer and of a new polymorph of the free ligand 3H-[1,2,3]triazolo[4,5-b]pyridin-3-ol [J] . Ghazzali M., Al-Farhan K., El-Faham A., Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2010,第14期

机译：配体7-氮杂-1-羟基-苯并三唑的配位化学。钴（II）甲醇配位聚合物-[μ-氯代（μ-7-氮杂-1-氧基-κ〜2N：O-苯并三唑基-κN）]钴和新的多晶型物的晶体结构和抗菌活性游离配体3H- [1,2,3]三唑[4,5-b]吡啶-3-醇
3. Poly[(μ-pentafluorobenzoato-κ2O:O′)(pentafluorobenzoato-κO)(μ-pyrazine-κ2N:N′)copper(II)]: a coordination polymer linked into a three-dimensional network by intermolecular C—H...F—C interactions [J] . Li-Juan Han, Ya-Jie Kong Acta crystallographica. Section C, Structural chemistry. . 2014,第11期

机译：聚[（μ-五氟苯并-κ2O：O'）（五氟苯并-κO）（μ-吡嗪-κ2N：N'）铜（II）：通过分子间CH连接成三维网络的配位聚合物。 .F—C交互
4. Synthesis and Crystal Structure of a New Copper(II) Coordination Polymer Cu(II)C_(16) H_(18) N_4O_4S_n [C] . LI Jia-gui, ZHU Wan-ren, DING Shu-hong, International Conference on Chemical Engineering and Advanced Materials . 2012

机译：新型铜（II）配位聚合物的合成和晶体结构Cu（II）C_（16）H_（18）N_4O_4S _N
5. Design, syntheses and characterization of copper(II) inorganic-organic hybrid coordination polymers based on beta-cyanodiketonates and telechelic nitrogenous spacers. [D] . Silvernail, Carter Martin. 2005

机译：基于β-氰基二酮酸酯和远螯氮间隔基的铜（II）无机-有机杂化配位聚合物的设计，合成和表征。
6. catena-Poly[diammonium [diaquabis(pyridine-2,4-dicarboxylato-κ2N,O2)cuprate(II)] [[diaquacopper(II)]-μ-pyridine-2,4-dicarboxylato-κ3N,O2:O2′-[tetraaquacadmium(II)]-μ-pyridine-2,4-dicarboxylato-κ3O2:N,O2′] hexahydrate] [O] . Guan-Hua Wang, Zhi-Gang Li, Heng-Qing Jia, 2016

机译：catena-Poly [二铵[diaquabis（pyridine-2,4-dicarboxylato-κ2）N，O2）铜酸盐（II）] [[透钙铜（II）]-μ-吡啶-2,4-二羧基羧基-κ3N，O2：哦2'-[四水合镉（II）]-μ-吡啶-2,4-二羧基羧基-κ3零2：N，O2']六水合物]
7. Poly[[chlorido(1,10-phenanthroline-κ2N,N′)copper(II)]-μ3-1,1,3,3-tetracyano-2-ethoxypropenido-κ3N:N′:N′′]: coordination polymer sheets linked into bilayers by hydrogen bonds [O] . Setifi, Z., Setifi, F., Ammari, L. El, 2014

机译：聚[[氯（1,10-菲咯啉-κ2N，N'）铜（II）]-μ3-1,1,3,3-四氰基-2-乙氧基丙烯-κ3N：N'：N'']：配位聚合物通过氢键连接成双层的片材
8. Inorganic Coordination Polymers. XXI. Manganese (II),Cobalt (II),Nickel (II),Copper (II),and Zinc (II) Bis(N-Phenylaminomethyl) Phosphinates. Effects of Coordinating Side Groups. [R] . eichelberger, j. l. gillman, h. d. 1977

机译：无机配位聚合物。 XXI。锰（II），钴（II），镍（II），铜（II）和锌（II）双（N-苯基氨基甲基）次膦酸盐。协调边群的影响。

Poly[[chlorido(1,10-phenanthroline-κ2N,N')copper(II)]-μ3-1,1,3,3-tetracyano-2-ethoxypropenido-κ3N:N':N'']: coordination polymer sheets linked into bilayers by hydrogen bonds.

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