A simple hydrated salt with a complex hydrogen-bonding network: Tetrakis(5-amino-3-carboxy-4H-1,2,4-triazol-1-ium) hexachloridocadmate(II) tetrahydrate

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A simple hydrated salt with a complex hydrogen-bonding network: Tetrakis(5-amino-3-carboxy-4H-1,2,4-triazol-1-ium) hexachloridocadmate(II) tetrahydrate

机译：具有复杂氢键网络的简单水合盐：四水合四（5-氨基-3-羧基-4H-1,2,4-三唑-1-鎓）六氯cadcadate（II）

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In the title cadmium chloride salt, (C3H5N 4O2)4[CdCl6] 4H2O, the asymmetric unit comprises two N-protonated 5-amino-3-carboxy-4H-1,2,4-triazol-1- ium cations, half a [CdCl6]4- anion and two molecules of water. The Cd2+ cation is located on a centre of inversion and is coordinated by six chloride anions, forming a distorted octahedron. In the crystal structure, alternating layers of cations and anions are arranged along the [101] direction, forming a three-dimensional supramolecular network via a combination of hydrogen-bonding and aromatic stacking interactions.

机译：在标题为（C3H5N 4O2）4 [CdCl6] 4H2O的氯化镉盐中，不对称单元包含两个N-质子化的5-氨基-3-羧基-4H-1,2,4-三唑-1-鎓阳离子，半个[CdCl6] 4-阴离子和两个分子的水。 Cd2 +阳离子位于反转中心，并与六个氯离子配位，形成扭曲的八面体。在晶体结构中，阳离子和阴离子的交替层沿[101]方向排列，通过氢键和芳族堆积相互作用的组合形成三维超分子网络。

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《Acta crystallographica. Section C, Structural chemistry.》 |2014年第7期|共5页
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正文语种 eng
中图分类晶体学;
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1; 2; 4-triazole; cadmium chloride salt; crystal structure; hybrid materials; hydrated salt; hydrogen bonding; materials chemistry;

机译：1;2;4-三唑;氯化镉盐;晶体结构;杂化材料;水合盐;氢键;材料化学;

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机译：具有复杂氢键网络的简单水合盐：四水合四（5-氨基-3-羧基-4H-1,2,4-三唑-1-鎓）六氯cadcadate（II）
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A simple hydrated salt with a complex hydrogen-bonding network: Tetrakis(5-amino-3-carboxy-4H-1,2,4-triazol-1-ium) hexachloridocadmate(II) tetrahydrate

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