Synthesis and crystal structure of a novel prochiral ketoimine: (E)-aceto-phenone O-diphenylphosphoryl oxime

Sean H. Majer Joseph M. Tanski

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Synthesis and crystal structure of a novel prochiral ketoimine: (E)-aceto-phenone O-diphenylphosphoryl oxime

机译：新型前手性酮亚胺的合成及晶体结构：（E）-乙酰苯O-二苯基磷酰基肟

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Asymmetric chemical synthesis methodologies that produce chiral resolved organic compounds have been of interest to chemists and chemical industry for many years (Blaser & Elke, 2004; Walsh & Kowzlowski, 2008). Treating compounds that contain prochiral carbonyl and imine carbon centers with nucleophiles, for example, has proven to be a valuable method for the synthesis of compounds with stereogenic centers (Silverio et al., 2013). Aldehydes and ketones may be used to produce chiral secondary alcohols (Baker-Salisbury et al. 2014) and tertiary alcohols (Garcia et al., 2002), respectively. Aldimine and ketoimine substrates may be used to prepare, respectively, chiral tertiary (Bonnaventure & Charette, 2009; Soai et al., 1992) and quaternary (Cogan & Ellman, 1999) hydrocarbon substituents on amines.

机译：多年以来，产生手性拆分的有机化合物的不对称化学合成方法已引起化学家和化学工业的关注（Blaser＆Elke，2004; Walsh＆Kowzlowski，2008）。例如，已证明用亲核试剂处理含有手性羰基和亚胺碳中心的化合物是合成具有立体异构中心的化合物的一种有价值的方法（Silverio等，2013）。醛和酮可分别用于生产手性仲醇（Baker-Salisbury等，2014）和叔醇（Garcia等，2002）。 Aldimine和ketoimine底物可分别用于制备胺上的手性叔烃（Bonnaventure＆Charette，2009; Soai等，1992）和季铵烃（Cogan＆Ellman，1999）。

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《Acta crystallographica. Section C, Structural chemistry.》 |2015年第3期|共4页
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Sean H. Majer Joseph M. Tanski;
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机译：新型前手性酮亚胺的合成及晶体结构：（E）-乙酰苯O-二苯基磷酰基肟
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Synthesis and crystal structure of a novel prochiral ketoimine: (E)-aceto-phenone O-diphenylphosphoryl oxime

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