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首页> 外文期刊>Acta crystallographica. Section C, Structural chemistry. >The synthesis, crystal structure and magnetic properties of a one-dimensional terbium(III)-octacyanido- molybdate(V) assembly
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The synthesis, crystal structure and magnetic properties of a one-dimensional terbium(III)-octacyanido- molybdate(V) assembly

机译:一维ter(Ⅲ)-八氰基钼酸酯(V)的合成,晶体结构和磁性

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摘要

There has been growing interest in the study of molecular magnets because of their promising applications. Recently, octacyanidometallate-based magnets have attracted much attention in molecular magnetism due to their variety of spatial configurations, e.g. square antiprism (D4d), dodecahedron (D2d) and bicapped trigonal prism (C2v) (Nowicka et al., 2012; Przychodzen et al., 2006; Sieklucka et al., 2005, 2009, 2011). In fact, the investigation of octacyanidometallate-based bimetallic systems has mainly focused on first-row transition metal ions (Freedman et al., 2006; Lim et al., 2006; Song et al. 2003,2005; Wang et al., 2010; Zhong et al., 2000). The synthesis of compounds containing octacyanidometallate (V) and lanthanide ions is still relatively challenging. Among these
机译:由于分子磁体的有前途的应用,人们对分子磁体的研究越来越感兴趣。近来,基于八氰基金属酸盐的磁体由于它们的多种空间构型,例如
分子结构,引起了分子磁性的极大关注。方形反棱镜(D4d),十二面体(D2d)和三角三角形棱镜(C2v)(Nowicka等,2012; Przychodzen等,2006; Sieklucka等,2005,2009,2011)。实际上,基于八氰基金属盐的双金属体系的研究主要集中在第一行过渡金属离子上(Freedman等,2006; Lim等,2006; Song等,2003,2005; Wang等,2010)。 ; Zhong et al。,2000)。含有金属氰化物(V)和镧系元素离子的化合物的合成仍然相对具有挑战性。在这些当中

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