Coordination polymer chains built from CuII and adipate ions linked by hydrogen bonds to form a three-dimensional framework structure

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Coordination polymer chains built from CuII and adipate ions linked by hydrogen bonds to form a three-dimensional framework structure

机译：由CuII和通过氢键连接的己二酸根离子构建的配位聚合物链形成三维骨架结构

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In the title compound, catena-poly[bis[(2,2'-bipyridine-κ2 N,N')(1,1,3,3-tetracyano-2-ethoxypropenido-κN)copper(II)]-μ4- hexanedioato-κ6 O1,O1':O 1:O6,O6':O6], [Cu2(C 9H5N4O)2(C6H 8O4)(C10H8N2) 2]n , the adipate (hexanedioate) dianion lies across a centre of inversion in the space group P . The CuII centre adopts a distorted form of axially elongated (4+2) coordination, and the CuII and adipate components form a one-dimensional coordination polymer from which the 2,2'-bipyridine and 1,1,3,3-tetracyano-2-ethoxypropenide components are pendent, and where each adipate dianion is bonded to four different Cu II centres. The coordination polymer chains are linked into a three-dimensional framework structure by a combination of C-H?N and C-H?O hydrogen bonds, augmented by a π-π stacking interaction.

机译：在标题化合物中，catena-聚[双[（2,2'-联吡啶-κ2N，N'）（1,1,3,3-四氰基-2-乙氧基丙烯-κN）铜（II）]-μ4-己二酮-κ6O1，O1'：O 1：O6，O6'：O6]，[Cu2（C 9H5N4O）2（C6H 8O4）（C10H8N2）2] n，己二酸（己二酸）二价阴离子跨过空间群P。 CuII中心采用扭曲的轴向延长（4 + 2）配位形式，CuII和己二酸酯组分形成一维配位聚合物，由该聚合物形成2,2'-联吡啶和1,1,3,3-四氰基- 2-乙氧基丙烯烯组分是侧基，并且每个己二酸二价阴离子键合到四个不同的Cu II中心。配位聚合物链通过C-H2N和C-H2O氢键的组合（通过π-π堆积相互作用而增强）连接成三维框架结构。

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《Acta crystallographica. Section C, Structural chemistry.》 |2014年第7期|共5页
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正文语种 eng
中图分类晶体学;
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1; 1; 3; 3-tetracyano-2-ethoxypropenide; 2; 2'-bipyridine; adipate; copper(II) complex; crystal structure; one-dimensional coordination polymer; polynitrile anions; π-π stacking interactions;

机译：1;1;3;3-四氰基-2-乙氧基丙烯;2;2'-联吡啶;己二酸酯;铜（II）络合物;晶体结构;一维配位聚合物;多腈阴离子;π-π堆积相互作用;

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1. Coordination polymer chains built from CuII and adipate ions linked by hydrogen bonds to form a three-dimensional framework structure [J] . Acta crystallographica. Section C, Structural chemistry. . 2014,第7期

机译：由CuII和通过氢键连接的己二酸根离子构建的配位聚合物链形成三维骨架结构
2. catena-Poly[[[4-amino-3,5-bis(pyridin-2-yl)-4H-1,2,4-triazole-κ2N1,N5](dicyanamido-κN)copper(II)]-μ2-dicyanamido-κ2N:N′]: coordination polymer chains linked into a bilayer by hydrogen bonds and π–π stacking interactions [J] . Setifi Zouaoui, Setifi Fatima, Saadi Mohamed, Acta crystallographica. Section C, Structural chemistry. . 2014,第4期

机译：阳离子多聚[[[[4-氨基-3,5-双（吡啶-2-基）-4H-1,2,4-三唑-κ2N1，N5]（双氰胺基-κN）铜（II）]-μ2- dicyanamido-κ2N：N']：配位聚合物链通过氢键和π-π堆积相互作用连接成双层
3. Tuning the formation of dicarboxylate linker-assisted supramolecular 1D chains and squares of Ni(II) using coordination and hydrogen bonds [J] . Khullar Sadhika, Gupta Vijay, Mandal Sanjay K. CrystEngComm . 2014,第25期

机译：使用配位和氢键调节二羧酸盐连接子辅助的Ni（II）的超分子一维链和正方形的形成
4. Design,Synthesis,and Characterization of Non-Covalently Linked Polymers by Hydrogen-Bonding and Coordination [C] . . -1

机译：非共价键键合聚合物的氢键配位设计，合成与表征
5. Self-Healing Polymer Nano-Composites via Hydrogen Bonding, and, Malleable, Self-Healing, Cross-linked Polymer Networks and Nano-Composites via Olefin Metathesis [D] . Lu, Yi-Xuan. 2014

机译：通过氢键结合的自修复聚合物纳米复合材料，以及通过烯烃复分解实现的可延展，自修复，交联的聚合物网络和纳米复合材料
6. (E)-N-{6-Chloro-4-(4-chlorophenyl)-3-methyl-1-phenyl-1H-pyrazolo34-bpyridin-5-ylmethylene}benzene-12-diamine: a three-dimensional framework structure built from only two hydrogen bonds [O] . Yurina Díaz, Jairo Quiroga, Justo Cobo, -1

机译：（E）-N-{6-氯-4-（4-氯苯基）-3-甲基-1-苯基-1H-吡唑并34-b吡啶-5-基亚甲基}苯-1 2-二胺：仅由两个氢键构成的三维骨架结构
7. Coordination polymer chains built from CuII and adipate ions linked by hydrogen bonds to form a three-dimensional framework structure [O] . Setifi, Z., Boutebdja, M., Setifi, F., 2014

机译：由CuII和通过氢键连接的己二酸根离子构建的配位聚合物链形成三维骨架结构

Coordination polymer chains built from CuII and adipate ions linked by hydrogen bonds to form a three-dimensional framework structure

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