Structure of pyrrhotite 5C (Fe_9S_(10))

Elliot A.D.

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Structure of pyrrhotite 5C (Fe_9S_(10))

机译：硫铁矿5C（Fe_9S_（10））的结构

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The distribution of vacancies throughout the underlying NiAs structure of pyrrhotite 5C was analysed through the application of vacancy avoidance and the closeness condition in conjunction with order-disorder layering. Two crystallographically equivalent structure solutions (chiral enantiomers) were produced consisting of layers containing one vacancy in every eight iron sites broken by a fully occupied layer every fifth iron layer, and best described by monoclinic statistical models. The statistical 5C structures were verified using synchrotron powder diffraction data as well as published electron-diffraction patterns. An order-disorder structure description is proposed for the intermediate pyrrhotites of which pyrrhotite 5C is an end-member.

机译：通过避免空位和紧密度条件以及有序无序分层，分析了黄铁矿5C底层NiAs结构中空位的分布。产生了两种晶体学上等效的结构溶液（手性对映异构体），该溶液由每八个铁位点包含一个空位的层组成，每五个铁层被一个完全占据的层打破，并且最好由单斜统计模型描述。统计5C结构使用同步加速器粉末衍射数据以及已发布的电子衍射图进行了验证。提出了以黄铁矿5C为末端成员的中间黄铁矿的无序结构描述。

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《Acta Crystallographica, Section B. Structural Science》 |2010年第3期|共9页
作者
Elliot A.D.;
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正文语种 eng
中图分类晶体学;
关键词
Distribution of vacancies; Order-disorder layering; Pyrrhotite; Synchrotron powder diffraction;

机译：空位分布;无序分层;硅黄铁矿;同步加速器粉末衍射;

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1. Structure of pyrrhotite 5C (Fe_9S_(10)) [J] . Elliot A.D. Acta Crystallographica, Section B. Structural Science . 2010,第3期

机译：硫铁矿5C（Fe_9S_（10））的结构
2. Redetermination of the structure of 5C pyrrhotite at low temperature and at room temperature [J] . Liles D.C., De Villiers J.P.R. The American mineralogist . 2012,第2a3期

机译：低温和室温下5C黄铁矿结构的重新测定
3. The crystal structure of a naturally occurring 5C pyrrhotite from Sudbury, its chemistry, and vacancy distribution [J] . Johan P.R. de Villiers, David C. Liles, Megan Becker American Mineralogist . 2009,第10期

机译：萨德伯里天然存在的5C硫铁矿的晶体结构，化学性质和空位分布
4. Risk Management of Terrorist Attacks in the Tunnels as Critical Points of Corridor 5c Infrastructure -Trans-European Road Network Through Bosnia and Herzegovina [C] . SamirAGIC, Edin GARAPLIJA NATO Advanced Research Workshop on Managing Terrorism Threats to Critical Infrastructure - Challenges for South Eastern Europe . 2015

机译：隧道恐怖袭击风险管理作为走廊5C基础设施 - 通过波斯尼亚和黑塞哥维那的欧洲道路网络的关键点
5. Studies of structures and phase transitions in pyrrhotite. [D] . Li, Fan. 1996

机译：黄铁矿的结构和相变研究。
6. Cofactors loaded quaternary structure of Lysine-specific demethylase 5C (KDM5C) protein: Computational model [O] . Yunhui Peng, Emil Alexov -1

机译：辅因子加载赖氨酸特异性脱甲基酶5C（KDM5C）蛋白的四级结构：计算模型
7. Studies of structures and phase transitions in pyrrhotite [O] . Li, Fan 1996

机译：黄铁矿的结构和相变研究
8. Studies of structures and phase transitions in pyrrhotite [R] . Li, F. 1997

机译：磁黄铁矿的结构和相变研究

Structure of pyrrhotite 5C (Fe_9S_(10))

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