The formation of (NH4)(2)V6O16 phase in the synthesized InVO4 for the hydrogen evolving applications

Lai Yu-Sheng; Yang Chih-Hsiang; Jehng Jih-Mirn

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The formation of (NH4)(2)V6O16 phase in the synthesized InVO4 for the hydrogen evolving applications

机译：在合成的INVO4中形成（NH4）（2）V6O16相对于氢不变应用

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By controlling the synthesized conditions such as the compositions, pH and hydrothermal temperature of the In (or NH4)-V-O compounds, the structural information have been determined with the potential application in the hydrogen evolving efficiency. When the addition of ammonium ions to adjust the pH with the hydrothermal time of 4 h, there is a maximum hydrogen production of 140.8 mu mol/g.cat. The maximum hydrogen production reaches at pH of 5. In addition, the (NH4)(2)V6O16 phase in the synthesized InVO4 has been observed. This crystalline ammonia vanadium-based material is capable to perform the photocatalysis process in hydrogen evolving.

机译：通过控制诸如in（或NH 4）-V-O化合物的组合物，pH和水热温度的合成条件，已经用氢不断发展效率的潜在应用确定了结构信息。当加入铵离子时用4小时的水热时间调节pH时，最大氢气产生140.8μmmol/ g.cat。在pH的pH下达到最大氢气产量5.此外，已经观察到合成的INVO4中的（NH 4）（2）V6O16相。该基于氨基钒基材料能够在氢气中进行光催化过程。

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来源
《Catalysis Communications》 |2018年第2018期|共5页
作者
Lai Yu-Sheng; Yang Chih-Hsiang; Jehng Jih-Mirn;
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作者单位

Natl Chung Hsing Univ Dept Chem Engn 250 Kuo Kuang Rd Taichung 402 Taiwan;

Natl Chung Hsing Univ Dept Chem Engn 250 Kuo Kuang Rd Taichung 402 Taiwan;

Natl Chung Hsing Univ Dept Chem Engn 250 Kuo Kuang Rd Taichung 402 Taiwan;

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原文格式 PDF
正文语种 eng
中图分类物理化学（理论化学）、化学物理学;
关键词
Hydrothermal synthesis; Photocatalysis; Hydrogen production; InVO4; (NH4)(2)V6O16;

机译：水热合成;光催化;氢气产量;INVO4;（NH4）（2）V6O16;

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1. The formation of (NH4)(2)V6O16 phase in the synthesized InVO4 for the hydrogen evolving applications [J] . Lai Yu-Sheng, Yang Chih-Hsiang, Jehng Jih-Mirn Catalysis Communications . 2018,第期

机译：在合成的INVO4中形成（NH4）（2）V6O16相对于氢不变应用
2. Phase Formation Behavior and Hydrogen Sensing Characteristics of Iron Oxide Nano-Particles Synthesized by Modified Pechini Route [J] . A. Ghosh, K. K. Atyam, K. Mukherjee, Materials Focus . 2016,第2期

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3. Preparation and formation mechanism of pure phase Ca_2Al-layered double hydroxides nanosheets synthesized by a T-type microchannel reactor: Application as hardening accelerator for mortar [J] . Pang Xiujiang, Liu Yuan, Chen Li, Applied clay science . 2018,第DECa期

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4. Structural Phase Transformations in KYF_4:Er~(3+) Nanoparticles Synthesized by Hydrothermal Method for Upconversion Applications [C] . S. Yamini, P. Sakthi Priya, M. Gunaseelan, DAE Solid State Physics Symposium . 2017

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5. Relationships between gas-phase ionization energies and solution-phase oxidation potentials: Applications to the electrocatalytic production of hydrogen from weak acids. [D] . Sakamoto, Takahiro. 2010

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6. Orientational disorder and phase transitions in ammonium oxofluorovanadates (NH4)3VOF5 and (NH4)3VO2F4 [O] . Anatoly A. Udovenko, Evgeny I. Pogoreltsev, Yuri V. Marchenko, -1

机译：（NH4）3VOF5和（NH4）3VO2F4氧代氟氟钒酸铵的取向紊乱和相变
7. High pressure structural, electronic, and optical properties of polymorphic InVO4 phases [O] . Mondal, S., Appalakondaiah, S., Vaitheeswaran, G. 2016

机译：高压结构，电子和光学性能多态InVO4阶段

The formation of (NH4)(2)V6O16 phase in the synthesized InVO4 for the hydrogen evolving applications

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