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首页> 外文期刊>Bulletin of the Chemical Society of Japan >Ordered Entanglement in Actinide-Organic Coordination Polymers
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Ordered Entanglement in Actinide-Organic Coordination Polymers

机译：滑动式 - 有机配位聚合物的有序缠结

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摘要

Entangled structures in actinide-organic hybrid materials featured by intertwining between isolated motifs show promising potential in the application of different fields, such as radionuclide separation, radiation detection, photocatalysis and smart materials. Since how the individual motifs are entangled in combination of molecular structures of the structural units and topology of the individual motifs contributes most to the properties of actinide entangled materials, it is of significance to summarize and analyze these entanglements with diverse topologies. For this contribution, we will summarize all the entanglements in the reported actinide-organic entangled structures by classifying them according to the diverse catalogues of individual motifs and entangled patterns between them, among which are included all these intriguing types of entanglement in different seperate sections: 1) polyrotaxanes; 2) parallel interpenetration (INT) and polycatenation (P-CAT and I-CAT); and 3) Borromean ring (BR). This work is aimed at figuring out some clues on design principles of actinide-organic entangled structures, the underlying rules of ordered entanglement and driving forces behind from our perspective so as to provide some valuable principles guiding the assembly process of entangled structures for reference and help to achieve the controlled syntheses of actinide compounds of interest in the future.
机译：在隔离基序之间交互的缠结结构中的缠绕结构在孤立的基序之间互联出来，在应用不同领域的应用方面具有潜力，例如放射性核素分离，辐射检测，光催化和智能材料。由于单个图案如何结合各个基序的结构单元和拓扑的分子结构的组合，从而大多数都有最重要的是缠绕材料的性质，总结和分析了各种拓扑的这些纠缠是重要的。对于这一贡献，我们将通过根据各个图案和它们之间的纠缠模式分类，总结报告的神奇内侧有机纠缠结构中的所有纠缠结构，其中包括不同单独的部分中的所有这些有趣类型的纠缠： 1）多岩; 2）平行互流（int）和多催化（p-cat和i-cat）; 3）Borromean环（BR）。这项工作旨在弄清楚有关Actinide-有机纠缠结构的设计原则的一些线索，从我们的角度来看，有序纠缠和驱动力的潜在规则，以提供一些有价值的原则，引导纠缠结构的纠结结构供参考和帮助为了实现未来感兴趣的无碱​​化化合物的控制合成。

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    Mei Lei; Shi Wei-qun; Chai Zhi-fang;

  • 作者单位

    Chinese Acad Sci Inst High Energy Phys Lab Nucl Energy Chem Beijing 100049 Peoples R China;

    Chinese Acad Sci Inst High Energy Phys Lab Nucl Energy Chem Beijing 100049 Peoples R China;

    Chinese Acad Sci Inst High Energy Phys Lab Nucl Energy Chem Beijing 100049 Peoples R China;

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  • 正文语种 eng
  • 中图分类 化学;
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