Synthesis of the Soluble Precursors of Tetrabenzoporphyrin: Control of the Solubility and the Conversion Temperature

Okujima Tetsuo; Hashimoto Yusuke; Furuta Tomoya; Yamanaka Ritsuko; Jin Guangnan; Otsubo Saika; Aramaki Shinji; Mori Shigeki; Yamada Hiroko; Uno Hidemitsu; One Noboru

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Synthesis of the Soluble Precursors of Tetrabenzoporphyrin: Control of the Solubility and the Conversion Temperature

机译：四苯并卟啉的可溶性前体的合成：控制溶解度和转化温度

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Novel thermally convertible precursors of tetrabenzoporphyrin (TBP) were synthesized by tetramerization of the corresponding bicyclo[2.2.2]octadiene(BCOD)-fused pyrroles. These precursors showed high solubility and were converted into TBPs by heating at 180-330 degrees C depending on the structure of BCOD moieties. This strategy provided easy access to pure PtTBP from the precursor with high conversion temperature in a good yield. Organic field effect transistors based on TBP were fabricated by thermal conversion after spin-coating of the precursors.

机译：通过四分之一的双环化（BCOD） - 用吡咯的四聚化，通过四聚化的四苯甲酰卟啉（TBP）的新型热转换前体。这些前体显示出高溶解度，并根据BCOD部分的结构，通过在180-330摄氏度下加热转化成Tbps。该策略可以轻松获得从前体的纯PTTBP，良好的屈服度高。基于TBP的有机场效应晶体管通过在前体的旋涂后热转化制备。

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来源
《Bulletin of the Chemical Society of Japan》 |2019年第8期|共9页
作者
Okujima Tetsuo; Hashimoto Yusuke; Furuta Tomoya; Yamanaka Ritsuko; Jin Guangnan; Otsubo Saika; Aramaki Shinji; Mori Shigeki; Yamada Hiroko; Uno Hidemitsu; One Noboru;
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作者单位

Ehime Univ Grad Sch Sci &

Engn 2-5 Bunkyo Cho Matsuyama Ehime 7908577 Japan;

Ehime Univ Grad Sch Sci &

Engn 2-5 Bunkyo Cho Matsuyama Ehime 7908577 Japan;

Ehime Univ Grad Sch Sci &

Engn 2-5 Bunkyo Cho Matsuyama Ehime 7908577 Japan;

Ehime Univ Grad Sch Sci &

Engn 2-5 Bunkyo Cho Matsuyama Ehime 7908577 Japan;

Ehime Univ Grad Sch Sci &

Engn 2-5 Bunkyo Cho Matsuyama Ehime 7908577 Japan;

Mitsubishi Chem Corp Yokohama Kanagawa 2278502 Japan;

Mitsubishi Chem Corp Yokohama Kanagawa 2278502 Japan;

Ehime Univ Res Unit Power Generat &

Storage Mat Matsuyama Ehime 7908577 Japan;

Nara Inst Sci &

Technol Grad Sch Mat Sci Ikoma Nara 6300192 Japan;

Ehime Univ Grad Sch Sci &

Engn 2-5 Bunkyo Cho Matsuyama Ehime 7908577 Japan;

Ehime Univ Grad Sch Sci &

Engn 2-5 Bunkyo Cho Matsuyama Ehime 7908577 Japan;

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原文格式 PDF
正文语种 eng
中图分类化学;
关键词
Tetrabenzoporphyrin; Retro Diels-Alder reaction; Organic field effect transistor;

机译：Tetrabenzoporyl;复古Diels-Alder反应;有机场效应晶体管;

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专利

1. Synthesis of the Soluble Precursors of Tetrabenzoporphyrin: Control of the Solubility and the Conversion Temperature [J] . Okujima Tetsuo, Hashimoto Yusuke, Furuta Tomoya, Bulletin of the Chemical Society of Japan . 2019,第8期

机译：四苯并卟啉的可溶性前体的合成：控制溶解度和转化温度
2. Synthesis of extremely soluble precursors of tetrabenzoporphyrins [J] . Okujima T, Hashimoto Y, Jin G, Tetrahedron . 2008,第10期

机译：四苯并卟啉极易溶解的前体的合成
3. Low-temperature synthesis of oil-soluble CdSe, CdS, and CdSe/CdS core - Shell nanocrystals by using various water-soluble anion precursors [J] . Pan DC, Wang Q, Jiang SC, The journal of physical chemistry, C. Nanomaterials and interfaces . 2007,第15期

机译：油溶性CdSe，CdS和CdSe / CdS核的低温合成-使用各种水溶性阴离子前体的壳纳米晶体
4. Soluble Pentacene Precursors: Strategic Design, Synthesis, and Characterization [C] . Tahsin J. Chow, Ta-Hsien Chuang, Hsin-Hui Huang, Organic field-effect transistors VII and organic semiconductors in sensors and bioelectronics . 2008

机译：可溶性并五苯前体：策略设计，合成和表征
5. Nanoparticles as reactive precursors: Synthesis of alloys, intermetallic compounds and multi-metal oxides through low-temperature annealing and conversion chemistry. [D] . Bauer, John Christopher. 2009

机译：纳米颗粒作为反应性前体：通过低温退火和转化化学合成合金，金属间化合物和多金属氧化物。
6. DopAmide: Novel Water‐Soluble Slow‐Release l‐dihydroxyphenylalanine (l‐DOPA) Precursor Moderates l‐DOPA Conversion to Dopamine and Generates a Sustained Level of Dopamine at Dopaminergic Neurons [O] . Daphne Atlas 2016

机译：DopAmide：新型水溶性缓释l-二羟基苯丙氨酸（l-DOPA）前体可将l-DOPA转化为多巴胺并在多巴胺能神经元上产生持续水平的多巴胺
7. A Theoretical Study on the Temperature Control of Fabrication of Pentacene Thin Film Transistors from Soluble Pentacene Precursors [O] . Kazuaki Yoshimura, Rumi Ishikawa, Hiroshi Miyazaki, 2010

机译：来自溶于戊烯前体的五价薄膜晶体管制备温度控制的理论研究
8. Self-Controlled Synthesis of Hyperbranched Polyetherketones From A3 + B2 Approach Via Different Solubilities of Monomers in the Reaction Medium (Preprint) [R] . Choi, J. , Baek, J. , Tan, L. 2006

机译：通过反应介质中单体的不同溶液从a3 + B2方法自控合成超支化聚醚酮（预印本）

Synthesis of the Soluble Precursors of Tetrabenzoporphyrin: Control of the Solubility and the Conversion Temperature

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